160504
9-Fluorenemethanol
99%
Synonym(s):
9-(Hydroxymethyl)fluorene, 9-Fluorenylmethanol
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About This Item
Empirical Formula (Hill Notation):
C14H12O
CAS Number:
Molecular Weight:
196.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
246-167-5
Beilstein/REAXYS Number:
2330017
MDL number:
Assay:
99%
Form:
solid
InChI key
XXSCONYSQQLHTH-UHFFFAOYSA-N
InChI
1S/C14H12O/c15-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14-15H,9H2
SMILES string
OCC1c2ccccc2-c3ccccc13
assay
99%
form
solid
mp
105-107 °C (lit.)
solubility
methanol: soluble 50 mg/mL, clear (very hazy colorless to yellow and Colorless to Green-Yellow)
functional group
hydroxyl
Quality Level
Related Categories
General description
Vibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH and 9-fluorenemethanol-C3H7OH has been studied by IR-UV double-resonance method. Electropolymerization of 9-fluorenemethanol in boron trifluoride diethyl etherate leads to low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) (PFMO) film.
Application
9-Fluorenemethanol, N-protecting reagent, was used in the peptide syntheses. 9-Fluorenemethanol was also used in the synthesis of deoxynucleoside 9-fluorenemethyl phosphorodithioates.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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The Journal of Organic Chemistry, 57, 6421-6421 (1992)
Low-potential electrosynthesis of novel electroactive poly (9-fluorenemethanol) and its electrochromic and blue-light-emitting properties.
Zhang S, et al.
Electrochimica Acta, 90, 452-460 (2013)
Journal of the American Chemical Society, 115, 4497-4497 (1993)
Synthesis, 119-119 (1990)
2'-Deoxynucleoside Dithiophosphates: Synthesis and Biological Studies1.
Seeberger PH, et al.
Journal of the American Chemical Society, 117(5), 1472-1478 (1995)
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