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Merck
CN

163015

Thallium(III) nitrate trihydrate

Synonym(s):

TTN, Thallium trinitrate

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About This Item

Linear Formula:
Tl(NO3)3 · 3H2O
CAS Number:
13453-38-8
Molecular Weight:
444.44
NACRES:
NA.22
PubChem Substance ID:
24850018
UNSPSC Code:
12161600
EC Number:
237-325-4
MDL number:
MFCD00149874

Key Documents

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InChI key

ZCPIKMRXMBJLCP-UHFFFAOYSA-N

InChI

1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3

SMILES string

O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

reaction suitability

core: thallium
reagent type: catalyst

mp

102-105 °C (lit.)

Quality Level

100

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Application

Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds, for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement, for the selective hydrolysis of thioacetals to carbonyl compounds and for a general synthetic method to 19-norsteroids. Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.

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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品
铊类化学品
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Certificates of Analysis (COA)

Lot/Batch Number
STBG4277V
STBJ6769
STBG3606V
STBG3605V
STBG3600V

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Articles

Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

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