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线性分子式:
Tl(NO3)3 · 3H2O
化学文摘社编号:
分子量:
444.44
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
反应适用性
core: thallium
reagent type: catalyst
mp
102-105 °C (lit.)
SMILES字符串
O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI
1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3
InChI key
ZCPIKMRXMBJLCP-UHFFFAOYSA-N
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应用
本试剂可用于将苯乙烯衍生物快速氧化成羰基化合物,用于通过氧化重排进行环芳烷基酮的区域选择性扩环反应,用于硫缩醛到羰基化合物的选择性水解以及用于 19-降甾族化合物的一般合成方法。介导环酮的缩环反应,生成一系列反式稠合的 10-甲基-2-萘烷酮。
警示用语:
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
储存分类代码
5.1B - Oxidizing hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
铊类化学品
此项目有
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Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis
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