17455
tert-Butyl α-bromoisobutyrate
≥98.0%
Synonym(s):
tert-Butyl 2-bromo-2-methylpropionate
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About This Item
Linear Formula:
(CH3)2CBrCOOC(CH3)3
CAS Number:
Molecular Weight:
223.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
245-924-7
Beilstein/REAXYS Number:
1905654
MDL number:
Assay:
≥98.0%
Quality Level
assay
≥98.0%
refractive index
n20/D 1.436
density
1.196 g/mL at 20 °C (lit.)
functional group
bromo, ester
SMILES string
CC(C)(C)OC(=O)C(C)(C)Br
InChI
1S/C8H15BrO2/c1-7(2,3)11-6(10)8(4,5)9/h1-5H3
InChI key
IGVNJALYNQVQIT-UHFFFAOYSA-N
Application
tert-Butyl α-bromoisobutyrate was used as an initiator in the atom transfer radical polymerisation (ATRP) of 2-(acetoacetoxy)ethyl methacrylate (AEMA).
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Protocols
Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.
Theodora Krasia et al.
Chemical communications (Cambridge, England), (4)(4), 538-539 (2003-03-18)
Reversible addition-fragmentation chain transfer (RAFT) radical polymerisation enables to synthesise well-defined homopolymers and block copolymers based on 2-(acetoacetoxy)ethyl methacrylate, which are capable to strongly coordinate to metals and metal ions.
Shin-Nosuke Nishimura et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(60), 15050-15058 (2017-08-11)
Precisely incorporating a wide range of structural and functional multiblocks along a polymer backbone is a significant challenge in polymer chemistry and offers promising opportunities to design highly ordered materials, including controlled polymer folding. Herein, a facile and versatile strategy
Global Trade Item Number
| SKU | GTIN |
|---|---|
| SML3416-25MG | 04065268780763 |
| SML3416-5MG | 04065268780770 |
| 17455-100ML | 04061838752000 |
| 17455-500ML | 04061836691387 |