179043
Borane N,N-diethylaniline complex
Synonym(s):
(N,N-Diethylaniline)trihydroboron, Diethylphenylamine-borane, NSC 239123
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About This Item
InChI key
YPWBYWNNJVSNPQ-UHFFFAOYSA-N
InChI
1S/C10H15N.BH3/c1-3-11(4-2)10-8-6-5-7-9-10;/h5-9H,3-4H2,1-2H3;1H3
SMILES string
B.CCN(CC)c1ccccc1
form
liquid
reaction suitability
reagent type: reductant
mp
−30-−27 °C (lit.)
density
0.917 g/mL at 25 °C (lit.)
functional group
amine
Quality Level
Related Categories
Application
- Diastereoselective reduction of prochiral enone intermediates
- Borylation of aryl halides
- Reductions of ketones, acids, esters, amides, and nitriles
- Investigations of borane source on enantioselectivity in enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones
Reactant for synthesis of:
- Chromanol derivatives as CETP inhibitors for the treatment of cardiovascular disease
- Allylic alcohols via enantioselective reductions
- Pinacolboranes for one-pot synthesis of unsymmetrical biaryls
signalword
Danger
hcodes
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
69.8 °F - closed cup
flash_point_c
21 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Flam. Liq. 2 - Water-react. 2
Regulatory Information
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