Key Documents

View All Documentation

179043

Borane N,N-diethylaniline complex

Name: Borane <I>N</I>,<I>N</I>-diethylaniline complex
Brand: ALDRICH

Synonym(s):

(N,N-Diethylaniline)trihydroboron, Diethylphenylamine-borane, NSC 239123

Select a Size

Change View

About This Item

Linear Formula:

C₆H₅N(C₂H₅)₂·BH₃

CAS Number:

13289-97-9

Molecular Weight:

163.07

NACRES:

NA.22

PubChem Substance ID:

24850794

UNSPSC Code:

12352116

EC Number:

236-305-2

MDL number:

MFCD00013187

Form:

liquid

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

form

liquid

Quality Segment

200

reaction suitability

reagent type: reductant

mp

−30-−27 °C (lit.)

density

0.917 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

B.CCN(CC)c1ccccc1

InChI

1S/C10H15N.BH3/c1-3-11(4-2)10-8-6-5-7-9-10;/h5-9H,3-4H2,1-2H3;1H3

InChI key

YPWBYWNNJVSNPQ-UHFFFAOYSA-N

Description

Application

Reactant for:

Diastereoselective reduction of prochiral enone intermediates
Borylation of aryl halides
Reductions of ketones, acids, esters, amides, and nitriles
Investigations of borane source on enantioselectivity in enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones

Reactant for synthesis of:

Chromanol derivatives as CETP inhibitors for the treatment of cardiovascular disease
Allylic alcohols via enantioselective reductions
Pinacolboranes for one-pot synthesis of unsymmetrical biaryls

pictograms

GHS02

signalword

Danger

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

69.8 °F - closed cup

flash_point_c

21 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Flam. Liq. 2 - Water-react. 2

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library