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179043

Borane N,N-diethylaniline complex

Name: Borane <I>N</I>,<I>N</I>-diethylaniline complex
Brand: ALDRICH

Synonym(s):

(N,N-Diethylaniline)trihydroboron, Diethylphenylamine-borane, NSC 239123

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About This Item

Linear Formula:

C₆H₅N(C₂H₅)₂·BH₃

CAS Number:

13289-97-9

Molecular Weight:

163.07

NACRES:

NA.22

PubChem Substance ID:

24850794

UNSPSC Code:

12352116

EC Number:

236-305-2

MDL number:

MFCD00013187

Form:

liquid

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Properties

form

liquid

Quality Segment

200

reaction suitability

reagent type: reductant

mp

−30-−27 °C (lit.)

density

0.917 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

B.CCN(CC)c1ccccc1

InChI

1S/C10H15N.BH3/c1-3-11(4-2)10-8-6-5-7-9-10;/h5-9H,3-4H2,1-2H3;1H3

InChI key

YPWBYWNNJVSNPQ-UHFFFAOYSA-N

Description

Application

Reactant for:

Diastereoselective reduction of prochiral enone intermediates
Borylation of aryl halides
Reductions of ketones, acids, esters, amides, and nitriles
Investigations of borane source on enantioselectivity in enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones

Reactant for synthesis of:

Chromanol derivatives as CETP inhibitors for the treatment of cardiovascular disease
Allylic alcohols via enantioselective reductions
Pinacolboranes for one-pot synthesis of unsymmetrical biaryls

pictograms

GHS02

signalword

Danger

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

69.8 °F - closed cup

flash_point_c

21 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Flam. Liq. 2 - Water-react. 2

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