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179647

Silver carbonate

Name: Silver carbonate
Brand: ALDRICH

99%

Synonym(s):

Disilver carbonate, Fetizon′s reagent, Silver tricarbonate

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About This Item

Linear Formula:

Ag₂CO₃

CAS Number:

534-16-7

Molecular Weight:

275.75

UNSPSC Code:

12352302

NACRES:

NA.23

PubChem Substance ID:

24850822

EC Number:

208-590-3

Beilstein/REAXYS Number:

6936654

MDL number:

MFCD00003403

Assay:

99%

Form:

powder and chunks

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Properties

Quality Level

200

assay

99%

form

powder and chunks

reaction suitability

core: silver, reagent type: catalyst

mp

210 °C (dec.) (lit.)

density

6.08 g/mL at 25 °C (lit.)

application(s)

PEM fuel cells
material synthesis precursor

SMILES string

[Ag]OC(=O)O[Ag]

InChI

1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

KQTXIZHBFFWWFW-UHFFFAOYSA-L

Description

General description

Silver carbonate,prepared by precipitation or ion-exchange method can behave as a visible light sensitive semiconductor photocatalyst.

Application

Silver carbonate (Ag₂CO₃)promotes the regioselective benzylation of carbohydrate derivatives in high yields. Ag₂CO₃ can be used as a base for the Pd catalysed oxyarylation of olefins by ortho-iodophenols.It can also be used for Koenigs-Knorr glycosylation.

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pictograms

GHS05,GHS09

signalword

Danger

hcodes

H318,H410

pcodes

P273 - P280 - P305 + P351 + P338 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Palladium-catalyzed oxyarylation of olefins using silver carbonate as the base. Probing the mechanism by electrospray ionization mass spectrometry.

Buarque CD, et al.

Journal of Organometallic Chemistry, 695(18), 2062-2067 (2010)

A novel high-efficiency visible-light sensitive Ag 2 CO 3 photocatalyst with universal photodegradation performances: Simple synthesis, reaction mechanism and first-principles study.

Dong H, et al.

Applied Catalysis. B, Environmental, 134, 46-54 (2013)

Photocatalytic behavior and photo-corrosion of visible-light-active silver carbonate/titanium dioxide.

Wang Y, et al

Materials Letters, 115, 85-88 (2014)

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Global Trade Item Number

SKU	GTIN
179647-25G	04061838754363
179647-100G	04061838754356
179647-5G	04061838754370