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Merck
CN

179647

碳酸银

99%

别名:

Disilver carbonate, Fetizon′s reagent, Silver tricarbonate

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关于此项目

线性分子式:
Ag2CO3
化学文摘社编号:
534-16-7
分子量:
275.75
Beilstein:
6936654
EC 号:
208-590-3
MDL编号:
MFCD00003403
UNSPSC代码:
12352302
PubChem化学物质编号:
24850822
NACRES:
NA.23

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质量水平

200

方案

99%

表单

powder and chunks

反应适用性

core: silver
reagent type: catalyst

mp

210 °C (dec.) (lit.)

密度

6.08 g/mL at 25 °C (lit.)

应用

PEM fuel cells
material synthesis precursor

SMILES字符串

[Ag]OC(=O)O[Ag]

InChI

1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

KQTXIZHBFFWWFW-UHFFFAOYSA-L

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相关类别

一般描述

通过沉淀 或离子交换 方法制备的碳酸银，可作为可见光敏感的半导体光催化剂。

应用

碳酸银（Ag2CO3）能够以高产率促进碳水化合物衍生物的区域选择性苄基化。Ag2CO3 可用作通过邻碘苯酚的Pd催化烯烃氧化的碱。它也可用于Koenigs-Knorr糖基化。

象形图

CorrosionEnvironment
GHS05,GHS09

警示用语：

Danger

危险声明

H318,H410

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCW9480
MKCZ2308
MKCW4881
MKCV9026
MKCT1590

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Palladium-catalyzed oxyarylation of olefins using silver carbonate as the base. Probing the mechanism by electrospray ionization mass spectrometry.
Buarque CD, et al.
Journal of Organometallic Chemistry, 695(18), 2062-2067 (2010)
A novel high-efficiency visible-light sensitive Ag 2 CO 3 photocatalyst with universal photodegradation performances: Simple synthesis, reaction mechanism and first-principles study.
Dong H, et al.
Applied Catalysis. B, Environmental, 134, 46-54 (2013)
Photocatalytic behavior and photo-corrosion of visible-light-active silver carbonate/titanium dioxide.
Wang Y, et al
Materials Letters, 115, 85-88 (2014)
A Ito et al.
The Journal of eukaryotic microbiology, 48(4), 440-448 (2001-07-18)
Infraciliature and morphogenesis of six rumen ciliates, Ostracodinium mammosum, O. munham, O. dilobum, O. rugoloricatum, O. iwawoi, and O. tiete are described from pyridinated silver carbonate-impregnated specimens. These six Ostracodinium have a similar polybrachykinety arrangement, distinct from that of other
Sukalyan Bhadra et al.
Journal of the American Chemical Society, 134(24), 9938-9941 (2012-06-12)
Decarboxylative Chan-Evans-Lam-type couplings are presented as a new strategy for the regiospecific construction of diaryl and alkyl aryl ethers starting from easily available aromatic carboxylic acids. They allow converting various aromatic carboxylate salts into the corresponding aryl ethers by reaction
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