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Merck
CN

18086

1-Ethyl-3-methylimidazolium methyl sulfate

≥98.0% (HPLC)

Synonym(s):

[EMIM][MS]

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About This Item

Empirical Formula (Hill Notation):
C7H14N2O4S
CAS Number:
Molecular Weight:
222.26
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Product Name

1-Ethyl-3-methylimidazolium methyl sulfate, ≥98.0% (HPLC)

InChI

1S/C6H11N2.CH4O4S/c1-3-8-5-4-7(2)6-8;1-5-6(2,3)4/h4-6H,3H2,1-2H3;1H3,(H,2,3,4)/q+1;/p-1

SMILES string

COS([O-])(=O)=O.CCn1cc[n+](C)c1

InChI key

BXSDLSWVIAITRQ-UHFFFAOYSA-M

assay

≥98.0% (HPLC)

composition

carbon, 37.07-38.58%
nitrogen, 12.35-12.85% (as tested by elemental analysis)

impurities

≤0.2% water

Quality Level

Application

[EMIM][MS] may be used as a solvent to synthesize gold nanoparticles via reduction of gold(III) chloride trihydrate [HAuCl4.3H2O] using glycerol as a reducing agent.

General description

1-Ethyl-3-methylimidazolium methyl sulfate [EMIM][MS] when added as an eluent modifier to the mobile phase results in better separation of the three positional isomers of benzoic acid by reversed-phase (RP) high-performance liquid chromatography (HPLC).

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Retention factors and resolutions of amino benzoic acid isomers with some lonic liquids.
Zheng J, et al.
Biotechnology and Bioprocess Engineering: BBE, 11(6), 477-483 (2006)
Effects of ionic liquid as additive and the pH of the mobile phase on the retention factors of amino benzoic acids in RP-HPLC.
Zheng J, et al.
Journal of Chromatographic Science, 45(5), 256-262 (2007)
Surface orientation of 1-methyl-, 1-ethyl-, and 1-butyl-3-methylimidazolium methyl sulfate as probed by sum-frequency generation vibrational spectroscopy
Santos, Cherry S., and Steven Baldelli
The Journal of Physical Chemistry B, 111.18, 4715-4723 (2007)
Effects of ionic liquid on the separation of 2-chlorophenol and 2, 4, 6-trichlorophenol in RP-HPLC
Zheng, J., and K. H. Row
Journal of Chromatographic Science, 47.5, 392-395 (2009)
Synthesis and characterization of gold nanoparticles using 1-alkyl, 3-methyl imidazolium based ionic liquids
Madu, A. N., et al.
International Journal of Physical Sciences, 6.4, 635-640 (2011)

Articles

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

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