183695
2′-Bromoacetophenone
99%
Synonym(s):
1-Acetyl-2-bromobenzene
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About This Item
Linear Formula:
BrC6H4COCH3
CAS Number:
Molecular Weight:
199.04
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
218-398-1
Beilstein/REAXYS Number:
1931534
MDL number:
Assay:
99%
Form:
liquid
Quality Level
assay
99%
form
liquid
refractive index
n20/D 1.568 (lit.)
density
1.476 g/mL at 25 °C (lit.)
functional group
bromo, ketone
SMILES string
CC(=O)c1ccccc1Br
InChI
1S/C8H7BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
InChI key
PIMNFNXBTGPCIL-UHFFFAOYSA-N
General description
2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.
Application
2′-Bromoacetophenone (2-Bromoacetophenone) was used in the synthesis of novel series of non-condensed 5,5-bicycles.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Palladium-catalysed convenient synthesis of 3-methyleneisoindolin-1-ones.
Cho CS, et al.
Synthetic Communications, 32(!2), 1821-1827 (2002)
Non-Condensed Trifluoromethylated 5, 5-Bicycles: Synthesis of 2-[3-Alkyl (phenyl)-1H-pyrazol-1-yl]-4-phenyl-5-alkylthiazole and-4, 5, 6, 7-tetrahydrobenzothiazole Systems.
Bonacorso HG, et al.
Synthesis, 2002(08), 1079-1083 (3003)
Enantioselective alkynylation of aromatic ketones catalyzed by chiral camphorsulfonamide ligands.
Gui Lu et al.
Angewandte Chemie (International ed. in English), 42(41), 5057-5058 (2003-11-05)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 183695-5G | 04061838756336 |
| 183695-25G | 04061838756329 |