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184667

(Chloromethyl)cyclopropane

Name: (Chloromethyl)cyclopropane
Brand: ALDRICH

97%

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About This Item

Linear Formula:

C₃H₅CH₂Cl

CAS Number:

5911-08-0

Molecular Weight:

90.55

NACRES:

NA.22

PubChem Substance ID:

24851125

UNSPSC Code:

12352100

EC Number:

227-632-1

MDL number:

MFCD00001307

Assay:

97%

Form:

liquid

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Properties

assay

97%

form

liquid

refractive index

n20/D 1.435 (lit.)

bp

87-89 °C (lit.)

density

0.98 g/mL at 25 °C (lit.)

functional group

chloro

SMILES string

ClCC1CC1

InChI

1S/C4H7Cl/c5-3-4-1-2-4/h4H,1-3H2

InChI key

ZVTQWXCKQTUVPY-UHFFFAOYSA-N

Description

General description

(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.

Application

(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.

pictograms

GHS02,GHS07

signalword

Danger

hcodes

H225,H315,H319,H335

pcodes

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

28.4 °F - closed cup

flash_point_c

-2 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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