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Merck
CN

186317

N,N-Diethylformamide

99%

Synonym(s):

N-Formyldiethylamine

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About This Item

Linear Formula:
HCON(C2H5)2
CAS Number:
617-84-5
Molecular Weight:
101.15
Beilstein:
1209392
EC Number:
210-533-2
MDL number:
MFCD00003287
UNSPSC Code:
12352100
PubChem Substance ID:
24851213
NACRES:
NA.22

Key Documents

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Quality Level

100

Assay

99%

form

liquid

refractive index

n20/D 1.434 (lit.)

bp

176-177 °C (lit.)

density

0.908 g/mL at 25 °C (lit.)

functional group

amide

SMILES string

CCN(CC)C=O

InChI

1S/C5H11NO/c1-3-6(4-2)5-7/h5H,3-4H2,1-2H3

InChI key

SUAKHGWARZSWIH-UHFFFAOYSA-N

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General description

N,N-Diethylformamide undergoes condensation with aromatic o-aminonitriles in the presence of ZnCl2 in sealed reactor to yield quinazoline-2,4(1H,3H)-dione.

Application

N,N-Diethylformamide was used in the synthesis of metal-organic frameworks. It was also used as solvent in the synthesis of porous cubic-shaped ZnO particles.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
SDBB5997
SDBB3826
STBL4390
STBL1292
STBK9233

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Yuxia Shen et al.
Advanced materials (Deerfield Beach, Fla.), 30(52), e1802497-e1802497 (2018-11-06)
Large-scale synthesis of van der Waals (vdW) metal-organic framework (MOF) nanosheets with controlled crystallinity and interlayer coupling strength is one of the bottlenecks in 2D materials that has limited its successful transition to large-scale applications. Here, scalable synthesis of mBDC
Yu Kimitsuka et al.
Inorganic chemistry, 52(24), 14028-14033 (2013-11-26)
A method for synthesizing porous cubic-shaped ZnO particles a few tens of micrometers in size is described on the basis of a pyrolytic conversion of Zn-terephthalate metal-organic frameworks (MOFs). MOF crystals were initially grown in solutions containing Zn(NO3)2·6H2O and terephthalic
G Amato et al.
Toxicology letters, 124(1-3), 11-19 (2001-10-31)
N-N, dimethyl- (DMF) and N-N, diethyl-formamide (DEF) are two hepatotoxic solvents, whose metabolism has not been investigated in humans. To identify the P450 isoforms involved in the microsomal oxidation of these solvents we used (a) 12 human liver samples; (b)
Renzo Arias-Ugarte et al.
Journal of the American Chemical Society, 134(2), 848-851 (2012-01-17)
We demonstrate that using Mo(CO)(6), Mo(CO)(5)NMe(3), and (η(5)-C(5)H(5))Mn(CO)(3) as catalysts for the silane, R(3)SiH, reduction of N,N-dimethylformamide (DMF), and N,N-diethylformamide (DEF), we can observe, intercept, and isolate, the important siloxymethylamine intermediates, R(3)SiOCH(2)NR'(2), R' = Me, Et, for the first time.
South African research into AIDS "cure" severely criticised.
P Sidley
BMJ (Clinical research ed.), 314(7083), 771-771 (1997-03-15)
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Articles

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

可持续能源技术中的金属有机骨架

金属有机骨架是配位聚合物的一部分，代表了大量替代能源应用的一个强大的新工具。通过提供定制的高表面积材料的简单的合成策略可以很容易获得MOF。

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