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About This Item
Empirical Formula (Hill Notation):
C10H20O5
CAS Number:
Molecular Weight:
220.26
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
251-379-6
Beilstein/REAXYS Number:
1618144
MDL number:
Assay:
98%
Form:
liquid
Quality Segment
assay
98%
form
liquid
reaction suitability
core: crown ether, reaction type: phase-transfer
refractive index
n
bp
93-96 °C/0.05 mmHg (lit.)
density
1.113 g/mL at 20 °C (lit.)
functional group
ether
SMILES string
O1CCOCCOCCOCCOCC1
InChI
1S/C10H20O5/c1-2-12-5-6-14-9-10-15-8-7-13-4-3-11-1/h1-10H2
InChI key
VFTFKUDGYRBSAL-UHFFFAOYSA-N
General description
15-Crown-5 is a crown ether generally used as a ligand in coordination chemistry because of its strong chelating property with certain alkali cations to form complexes. Some derivatives of 15-crown-5 are used as sensors and probes in different physical-chemical processes, phase-transfer reactions, and selective capture of ions for separation and transport.
Application
15-Crown-5 is a crown ether that is generally used as a ligand in coordination chemistry. It shows the ability to complexes with alkali metal ions.
15-Crown-5 can be used:
- As a phase transfer catalyst for the preparation of polyphenylacetylene (PPA) by anionic polymerization of phenylacetylene with sodium amide (NaNH2).
- In the allylic alkylation of allyl acetates by malonates with palladium complex catalysts.
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Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
10 - Combustible liquids
WGK
WGK 3
PPE (personal protective equipment)
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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