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189979

N,N-Dimethylformamide-d7

≥99.5 atom % D

Synonym(s):

DMF-d7, Heptadeutero-N,N-dimethylformamide

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About This Item

Linear Formula:
DCON(CD3)2
CAS Number:
4472-41-7
Molecular Weight:
80.14
UNSPSC Code:
12142201
NACRES:
NA.21
PubChem Substance ID:
24851409
MDL number:
MFCD00003286
Beilstein/REAXYS Number:
1908468
Isotopic purity:
≥99.5 atom % D
Assay:
≥99% (CP)
Mass shift:
M+7
Form:
liquid
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isotopic purity

≥99.5 atom % D

Quality Level

200

assay

≥99% (CP)

form

liquid

technique(s)

NMR: suitable

impurities

≤0.05% water
water

refractive index

n20/D 1.428 (lit.)

bp

153 °C (lit.)

density

1.03 g/mL at 25 °C (lit.)

mass shift

M+7

SMILES string

[2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H]

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3D

InChI key

ZMXDDKWLCZADIW-YYWVXINBSA-N

General description

N,N-Dimethylformamide-d7 (DMF-d7) is a deuterated derivative of N,N-dimethylformamide. It has an isotopic purity of 99.5atom%D. It is a standard purity solvent suitable for routine NMR analyses (conducted at ambient temperatures where quality is less critical). It participates as a solvent to evaluate the solvation of 1.7molar solution of lithium chloride (LiCl) by pulsed neutron diffraction studies. Quadrupole splittings and quadrupole coupling constants of DMF-d7 oriented in a nematic phase have been evaluated by deuteron magnetic resonance studies. DMF-d7 is being considered as a potent anti-cancer drug.

Application

N,N-Dimethylformamide-d7 may be used to study its metabolism in rats by 2H NMR spectroscopy.

Other Notes

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

135.5 °F - closed cup

flash_point_c

57.5 °C - closed cup

Regulatory Information

危险化学品
美国出口管控产品

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Certificates of Analysis (COA)

Lot/Batch Number
MBBF1147
MBBF1146
MBBD3719
MBBD3716
MBBD3710

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Articles

NMR Deuterated Solvent Properties Reference Chart

Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.

Related Content

Investigation of the feasibility of directly-coupled HPLC-NMR with 2H detection with application to the metabolism of N-dimethylformamide-d7.
Farrant RD, et al.
Journal of Pharmaceutical and Biomedical Analysis, 16(1), 1-5 (1997)
Deuterium NMR spectroscopy of biofluids for the identification of drug metabolites: application to N, N-dimethylformamide.
Farrant RD, et al.
Journal of Pharmaceutical and Biomedical Analysis, 11(8), 687-692 (1993)
NMR determination of quadrupole coupling constants of deuterons in N, N-dimethylformamide-d7.
Balakrishnan NS.
Journal of Magnetic Resonance, 83(2), 233-245 (1989)
View All Related Papers

Global Trade Item Number

SKUGTIN
189979-10X1ML04061838759566
189979-10X0.75ML04061838759559
189979-5X0.5ML04061838759580
189979-10X1G-N04061837613630
189979-1G04061837613647
189979-5X10G-NA04061837649295
189979-5X10G-N04061837649288
189979-10G04061838759542
189979-5G04061838759573