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Merck
CN

191124

Poly(methyl vinyl ether-alt-maleic acid)

average Mw ~216,000 by LS, average Mn ~80,000, powder

Synonym(s):

Maleic acid-methyl vinyl ether copolymer, Methoxyethylene-maleic acid copolymer, Poly(maleic acid-methyl vinyl ether), Vinyl methyl ether-maleic acid copolymer

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About This Item

Linear Formula:
[CH2CH(OCH3)CH(CO2H)CH(CO2H)]n
CAS Number:
25153-40-6
NACRES:
NA.23
PubChem Substance ID:
24851468
UNSPSC Code:
12162002
MDL number:
MFCD00133997

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InChI

1S/C4H4O4.C3H6O/c5-3(6)1-2-4(7)8;1-3-4-2/h1-2H,(H,5,6)(H,7,8);3H,1H2,2H3/b2-1-;

SMILES string

COC=C.OC(=O)\C=C\C(O)=O

InChI key

HHEHWCIYDICHCG-ODZAUARKSA-N

form

powder

mol wt

average Mn ~80,000, average Mw ~216,000 by LS

pH

~2.5 (5% in H2O)

Quality Level

200

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General description

Poly(methyl vinyl ether-alt-maleic acid) (PMVEMA) is a hydrophilic polymer which is biocompatible with bioadhesive properties. It is an acidic polymer that can be used to improve the stability and zeta potential of polyaniline (PANI) solution.

Application

Detergent builder.
PMVEMA can be cross-linked with cellulose whiskers for the formation of nanocomposite films for potential usage in medical and food packaging applcations. It can also be conjugated with polyethylene glycol (PEG) to form hydrogels which can be used in drug delivery systems.

Features and Benefits

Dissolves readily in water, chelates alkaline earth cations but not toxic heavy metal ions.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ8563
MKCX7272
MKCW6386
MKCW2116
MKCV9873

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A novel nanocomposite film prepared from crosslinked cellulosic whiskers
Goetz L, et al.
Carbohydrate Polymers, 75(1), 85-89 (2009)
The Effect of Poly (methyl vinyl ether-alt-maleic acid) Stabilizer on the Stability of Polyaniline-Poly (methyl vinyl ether-alt-maleic acid) Dispersions
Koo CM, et al.
Journal of Colloid and Interface Science, 227(2), 316-321 (2000)
Poly (methyl vinyl ether-alt-maleic acid)-Functionalized Porous Silicon Nanoparticles for Enhanced Stability and Cellular Internalization
Shahbazi M, et al.
Macromolecular Rapid Communications, 35(6), 624-629 (2014)
Hydrogels prepared from cross-linked nanofibrillated cellulose
Nair SS, et al.
ACS sustainable chemistry & engineering, 2(4), 772-780 (2014)

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