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Merck
CN

195030

Triethylborane solution

1.0 M in hexanes

Synonym(s):

Triethylboron

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About This Item

Linear Formula:
(C2H5)3B
CAS Number:
97-94-9
Molecular Weight:
97.99
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
24851669
MDL number:
MFCD00009022
Beilstein/REAXYS Number:
1731462

Key Documents

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Product Name

Triethylborane solution, 1.0 M in hexanes

InChI

1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3

SMILES string

CCB(CC)CC

InChI key

LALRXNPLTWZJIJ-UHFFFAOYSA-N

form

liquid

reaction suitability

reagent type: reductant

concentration

1.0 M in hexanes

density

0.675 g/mL at 25 °C

Quality Level

100

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Application

Catalyst for:
  • Allylation of aldehydes
  • Decarboxylative C-C bond cleavage reactions
  • Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations
  • Regioselective hydroxyalkylation of unsaturated oxime ethers

Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes

Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential
Triethylborane can be used:
  • As a radical initiator and terminator of free-radical reactions in aqueous media.(1)
  • To synthesize polymers such as poly(2-substituted-1-propenylene)s by reacting with 2-substituted allylic arsonium ylides.(2)

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1A - STOT RE 1 Inhalation - STOT SE 3

target_organs

Central nervous system, Nervous system

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

-32.8 °F

flash_point_c

-36 °C

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
0000510552
0000510552
0000498616
0000498616
0000423638

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Free-radical reaction of imine derivatives in water.
Miyabe H, et al.
The Journal of Organic Chemistry, 65(16), 5043-5047 (2000)
Synthesis of poly (2-substituted-1-propenylene)s from allylic arsonium ylides.
Mondiere R, et al.
Macromolecules, 38(3), 663-668 (2005)
Hideto Miyabe et al.
Chemical & pharmaceutical bulletin, 52(7), 842-847 (2004-07-17)
Tandem radical addition-cyclization of oxime ethers anchored to polymer support was studied. The reaction of oxime ethers with stannyl radical proceeded effectively by the use of triethylborane as a radical initiator. The alkyl radical addition-cyclization reactions of oxime ether connected
H Miyabe
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 120(8), 667-676 (2000-08-18)
Triethylborane has the potential to induce radical reactions on solid support and the solid-phase radical reactions were achieved by using triethylborane as a radical initiator. The intermolecular carbon radical addition to glyoxylic oxime ether anchored to Wang resin proceeded under
Masamichi Nakakoshi et al.
Magnetic resonance in chemistry : MRC, 44(8), 807-812 (2006-05-27)
The structures of the components in the triethylborane-mediated radical addition reaction of oxime ether were investigated by 1H- and 3D-DOSY NMR methods. It has been impossible to physically separate the unstable intermediates; therefore, the structures were thus far unidentified. It
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