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Merck
CN

195324

Sigma-Aldrich

2-Bromopyridine N-oxide hydrochloride

97%

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About This Item

Empirical Formula (Hill Notation):
C5H4BrNO · HCl
CAS Number:
Molecular Weight:
210.46
EC Number:
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
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Assay

97%

mp

131-134 °C (lit.)

functional group

bromo

SMILES string

Cl[H].[O-][n+]1ccccc1Br

InChI

1S/C5H4BrNO.ClH/c6-5-3-1-2-4-7(5)8;/h1-4H;1H

InChI key

FRYPQGMFDZBQEW-UHFFFAOYSA-N

Application

2-Bromopyridine N-oxide hydrochloride can be used as a reactant to prepare:
  • A complex of pyridine-N-oxide with borane by reacting with alkynyltriarylborates.
  • A biologically significant bis(2-selenopyridine-N-oxide)nickel(II)-acetone complex.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of Pyridine-N-oxide-Borane Intramolecular Complexes by Palladium-Catalyzed Reaction of 2-Bromopyridine-N-oxides with Alkynyltriarylborates
Ishida N, et al.
Organic Letters, 13(12), 3008-3011 (2011)
Crystal structure of bis (2-selenopyridine-N-oxide) nickel (II)--acetone (1:0.25), [Ni(C5H4NOSe)2]. 0.25 C3H6O
Niu D-Z, et al.
Zeitschrift fur Kristallographie - New Crystal Structures, 224(2), 327-328 (2009)

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