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195936

3-(Perfluorobutyryl)-(+)-camphor

Name: 3-(Perfluorobutyryl)-(+)-camphor
Brand: ALDRICH

96%

Synonym(s):

(+)-3-(Heptafluorobutyryl)-(+)-camphor, 3-(Perfluorobutyryl)-D-camphor

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About This Item

Empirical Formula (Hill Notation):

C₁₄H₁₅F₇O₂

CAS Number:

51800-99-8

Molecular Weight:

348.26

UNSPSC Code:

12352115

NACRES:

NA.22

PubChem Substance ID:

24851726

EC Number:

257-430-9

Beilstein/REAXYS Number:

2306496

MDL number:

MFCD00064154

Assay:

96%

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Properties

Quality Level

200

assay

96%

optical activity

[α]20/D +125°, c = 2.6 in chloroform

refractive index

n20/D 1.421 (lit.)

bp

60-70 °C/0.2 mmHg (lit.)

density

1.218 g/mL at 25 °C (lit.)

functional group

fluoro, ketone

SMILES string

CC1(C)C2CC[C@@]1(C)C(=O)C2C(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C14H15F7O2/c1-10(2)6-4-5-11(10,3)8(22)7(6)9(23)12(15,16)13(17,18)14(19,20)21/h6-7H,4-5H2,1-3H3/t6-,7?,11+/m1/s1

InChI key

PEWOESYEGLBLNR-XGLFCGLISA-N

Description

Application

3-(Perfluorobutyryl)-(+)-camphor can be used:

As a ligand in the synthesis of chiral europium complex for optoelectronic and photonic applications.
As a ligand in the preparation of sodium tetrakis(3-heptafluorobutylryl-(+)-camphorato) Ln(III) complexes applicable as chemical sensors and NMR shift reagents.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

199.4 °F - closed cup

flash_point_c

93 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Highly circularly polarized electroluminescence from a chiral europium complex

Zinna F, et al.

Advanced Materials, 27(10), 1791-1795 (2015)

Novel Configurational Structures of Sodium Tetrakis (3-heptafluorobutylryl-(+)-camphorato) Ln (III) Complexes with a Trapped Na+ by Na+?FC Interactions in the Solid State and in Solution

Shirotani D, et al.

Inorganic Chemistry, 45(16), 6111-6113 (2006)

Global Trade Item Number

SKU	GTIN
195936-5G	04061837392313