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Merck
CN

200956

Hexafluorophosphoric acid solution

~55 wt. % in H2O

Synonym(s):

Hydrogen hexafluorophosphate

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About This Item

Linear Formula:
HPF6
CAS Number:
16940-81-1
Molecular Weight:
145.97
NACRES:
NA.22
PubChem Substance ID:
24851984
UNSPSC Code:
12352301
MDL number:
MFCD00011350

Key Documents

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Product Name

Hexafluorophosphoric acid solution, ~55 wt. % in H2O

InChI

1S/F5P.FH/c1-6(2,3,4)5;/h;1H

SMILES string

F.FP(F)(F)(F)F

InChI key

OQWOLAMXNGPSQY-UHFFFAOYSA-N

form

liquid

concentration

~55 wt. % in H2O

density

1.651 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

100

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Application

Hexafluorophosphoric acid solution is used as a catalyst for the conversion of polyethyleneimine (PEI) microgel into the corresponding polymeric ionic liquids (PIL) forms via protonation and anion exchange reaction. Polymeric ionic liquids are used as metal-free catalysts for hydrogen production via sodium borohydride methanolysis.

General description

Hexafluorophosphoric acid (HPF6) is a strong acid that is commonly used as a catalyst in organic synthesis. It is also used in the polymerization and preparation of its salts.

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCR7412
MKCR7413
MKCN3283
MKCM5356
SHBK2376

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Product Class 12: Telluropyrylium and Benzotelluropyrylium Salts
Murphy PJ et al.
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations null
The Use of Hexafluorophosphoric Acid in the Schiemann Reaction
Rutherford KG, et al.
The Journal of Organic Chemistry, 26(12), 5149-5152 (1961)

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