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Merck
CN

200956

Hexafluorophosphoric acid solution

~55 wt. % in H2O

Synonym(s):

Hydrogen hexafluorophosphate

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About This Item

Linear Formula:
HPF6
CAS Number:
Molecular Weight:
145.97
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352301
MDL number:
Concentration:
~55 wt. % in H2O
Form:
liquid
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form

liquid

Quality Level

concentration

~55 wt. % in H2O

density

1.651 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

F.FP(F)(F)(F)F

InChI

1S/F5P.FH/c1-6(2,3,4)5;/h;1H

InChI key

OQWOLAMXNGPSQY-UHFFFAOYSA-N

General description

Hexafluorophosphoric acid (HPF6) is a strong acid that is commonly used as a catalyst in organic synthesis. It is also used in the polymerization and preparation of its salts.

Application

Hexafluorophosphoric acid solution is used as a catalyst for the conversion of polyethyleneimine (PEI) microgel into the corresponding polymeric ionic liquids (PIL) forms via protonation and anion exchange reaction. Polymeric ionic liquids are used as metal-free catalysts for hydrogen production via sodium borohydride methanolysis.


pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Articles

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.


The Use of Hexafluorophosphoric Acid in the Schiemann Reaction
Rutherford KG, et al.
The Journal of Organic Chemistry, 26(12), 5149-5152 (1961)
Product Class 12: Telluropyrylium and Benzotelluropyrylium Salts
Murphy PJ et al.
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations null



Global Trade Item Number

SKUGTIN
200956-25G04061838763969
200956-500G04061838763976