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Merck
CN

201049

Lithium hydride

greener alternative

powder, −30 mesh, ≥95%

Synonym(s):

LiH

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About This Item

Linear Formula:
LiH
CAS Number:
Molecular Weight:
7.95
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
231-484-3
MDL number:
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InChI key

SIAPCJWMELPYOE-UHFFFAOYSA-N

InChI

1S/Li.H

SMILES string

[Li]

assay

≥95%

form

powder

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
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sustainability

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particle size

−30 mesh

mp

680 °C (lit.)

density

0.82 g/mL at 25 °C (lit.)

greener alternative category

Quality Level

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General description

Lithium hydride is a simple neutral heteropolar diatomic molecule. It liberates hydrogen upon heating it to temperatures above 500oC. Lithium hydride, like lithium aluminum hydride, exhibits a high gravimetric hydrogen storage capacity. LiH is known to have large specific heat and latent heat of fusion.5
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Application

Lithium hydride may be used as an effective neutron shield for mobile nuclear reactors. LiH may also be used as a rocket fuel, energy storage system, and heat shield.5

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Skin Corr. 1B - Water-react. 1

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

监管及禁止进口产品
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Thermophysical Properties of Chemicals and Hydrocarbons null
Lithium hydride: A space age shielding material
Welch FH
Nuclear Engineering and Design, 26(3), 444-460 (1974)
Kiyotaka Goshome et al.
Molecules (Basel, Switzerland), 24(7) (2019-04-10)
Hydrogenation of a lithium-potassium (double-cation) amide (LiK(NH₂)₂), which is generated as a product by ammonolysis of litium hydride and potassium hydride (LiH-KH) composite, is investigated in details. As a result, lithium amide (LiNH₂) and KH are generated after hydrogenation at
Josué A Torres-Ávalos et al.
Polymers, 13(4) (2021-03-07)
Design of a smart drug delivery system is a topic of current interest. Under this perspective, polymer nanocomposites (PNs) of butyl acrylate (BA), methacrylic acid (MAA), and functionalized carbon nanotubes (CNTsf) were synthesized by in situ emulsion polymerization (IEP). Carbon
Volodymyr Gvozdetskyi et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(16), 4123-4135 (2019-01-17)
Ternary lithium nickel borides LiNi3 B1.8 and Li2.8 Ni16 B8 have been synthesized by using reactive LiH as a precursor. This synthetic route allows better mixing of the precursor powders, thus facilitating rapid preparation of the alkali-metal-containing ternary borides. This

Articles

Mechanochemical Effect of Severe Plastic Deformations: Metal Alloys, Hydrides and Molecular Solids

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