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Merck
CN

201146

Lithium hexafluorophosphate

98%

Synonym(s):

Lithium phosphorus fluoride

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About This Item

Linear Formula:
LiPF6
CAS Number:
Molecular Weight:
151.91
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
244-334-7
MDL number:
Assay:
98%
Form:
powder
Solubility:
H2O: slightly soluble(lit.)
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Quality Segment

assay

98%

form

powder

reaction suitability

core: lithium

mp

200 °C (dec.) (lit.)

solubility

H2O: slightly soluble(lit.)

density

1.5 g/mL (lit.)

application(s)

battery precursors
catalysts
material synthesis precursor

SMILES string

[Li+].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

InChI key

AXPLOJNSKRXQPA-UHFFFAOYSA-N

General description

Lithium hexafluorophosphate is a white to off-white color compound that comes in powder or chunk form and is widely used in electrochemical applications, particularly in lithium-ion batteries.

Application

The main use of LiPF6 is as an electrolyte salt in lithium-ion batteries. It plays a crucial role in the electrolyte solution, enhancing overall ionic conductivity and electrochemical stability. This makes it vital for R&D applications in high-performance batteries in consumer electronics, electric vehicles, and energy storage systems. LiPF6 assists in forming a stable SEI layer on the anode, which is essential for the durability and reliability of lithium-ion batteries. This layer helps prevent degradation and improves battery safety. LiPF6 is useful in R&D applications for the production of thin films and coatings for various electronic and optical applications, enhancing the performance and stability of these materials. It can be used as a catalyst or catalyst component in various organic synthesis reactions, particularly those requiring a strong Lewis acid.

Features and Benefits

  • It can form suitable SEI membranes in electrodes, especially in the cathode
  • It can implement passivation for anode current collectors to prevent their dissolution
  • Wide windows of electrical stability
  • Excellent solubility and high conductivity in various solvents
  • Environment-friendly


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Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation

target_organs

Bone,Teeth

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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