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Merck
CN

203475

Ammonium hexachloroiridate(IV)

99.99% trace metals basis

Synonym(s):

Iridium(IV)-ammonium chloride

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About This Item

Linear Formula:
(NH4)2IrCl6
CAS Number:
16940-92-4
Molecular Weight:
441.01
NACRES:
NA.23
PubChem Substance ID:
24852174
UNSPSC Code:
12352302
EC Number:
241-007-0
MDL number:
MFCD00010881
Assay:
99.99% trace metals basis
Form:
powder

Key Documents

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InChI key

LWNOUTCTZQNGEN-UHFFFAOYSA-J

InChI

1S/6ClH.Ir.2H3N/h6*1H;;2*1H3/q;;;;;;+4;;/p-4

SMILES string

[H][N+]([H])([H])[H].[H][N+]([H])([H])[H].Cl[Ir--](Cl)(Cl)(Cl)(Cl)Cl

assay

99.99% trace metals basis

form

powder

impurities

≤150 ppm Trace metallic impurities analysis (ICP)

density

2.86 g/mL at 25 °C (lit.)

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS7321
02925JX
10209BE
12801LD
13326BC

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Na Song et al.
Inorganic chemistry, 47(24), 11458-11460 (2008-11-14)
One-electron oxidation of phenol, 2,4,6-trimethylphenol, and 2,6-dimethylphenol by [IrCl(6)](2-) in aqueous solution has a simple pH dependence, indicating slow bimolecular oxidation of ArOH and faster oxidation of ArO(-). H/D kinetic isotope effects as large as 3.5 for oxidation of ArOH
Z S Farhangrazi et al.
Biochemistry, 34(46), 14970-14974 (1995-11-21)
Horseradish peroxidase (HRP) was oxidized by IrCl6(2-) to a mixture of compounds I and II, the rate of oxidation and the ratio of the mixture being greatly affected by pH (Hayashi & Yamazaki, 1979). Oxidation of HRP by IrCl6(2-) in
Fabrizio Testa et al.
Free radical biology & medicine, 51(8), 1567-1574 (2011-08-16)
Unlike superoxide dismutases (SODs), superoxide reductases (SORs) eliminate superoxide anion (O(2)(•-)) not through its dismutation, but via reduction to hydrogen peroxide (H(2)O(2)) in the presence of an electron donor. The microaerobic protist Giardia intestinalis, responsible for a common intestinal disease
Y Kaneko et al.
Biochemistry, 19(25), 5795-5799 (1980-12-09)
Zinc-substituted horseradish peroxidase is oxidized by K2IrCl6 to a characteristic state which retains one oxidizing equivalent more than the zinc peroxidase. The oxidized enzyme gives an optical absorption spectrum similar to that of compound I of peroxidase and catalase, and
J G Muller et al.
Nucleic acids research, 26(9), 2247-2249 (1998-06-20)
Two gel electrophoretic methods are described for detection of 7, 8-dihydro-8-oxoguanine and 7,8-dihydro-8-oxoadenine based on their further oxidation with one-electron oxidants including IrCl62-and IrBr62-. The products of nucleobase oxidation lead to enhanced piperidine-sensitive cleavage and to highly visible stop points
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