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Merck
CN

203475

Ammonium hexachloroiridate(IV)

99.99% trace metals basis

Synonym(s):

Iridium(IV)-ammonium chloride

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About This Item

Linear Formula:
(NH4)2IrCl6
CAS Number:
16940-92-4
Molecular Weight:
441.01
NACRES:
NA.23
PubChem Substance ID:
24852174
UNSPSC Code:
12352302
EC Number:
241-007-0
MDL number:
MFCD00010881
Assay:
99.99% trace metals basis
Form:
powder

Key Documents

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InChI key

LWNOUTCTZQNGEN-UHFFFAOYSA-J

InChI

1S/6ClH.Ir.2H3N/h6*1H;;2*1H3/q;;;;;;+4;;/p-4

SMILES string

[H][N+]([H])([H])[H].[H][N+]([H])([H])[H].Cl[Ir--](Cl)(Cl)(Cl)(Cl)Cl

assay

99.99% trace metals basis

form

powder

impurities

≤150 ppm Trace metallic impurities analysis (ICP)

density

2.86 g/mL at 25 °C (lit.)

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS7321
02925JX
10209BE
12801LD
13326BC

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V Duarte et al.
Nucleic acids research, 27(2), 496-502 (1998-12-24)
Oxidative damage to DNA bases commonly resultsin the formation of oxidized purines, particularly 7,8-dihydro-8-oxoguanine (8-oxoG) and 7,8-dihydro-8-oxoadenine (8-oxoA), the former being a well-known mutagenic lesion. Since 8-oxoG is readily subject to further oxidation compared with normal bases, the insertion of
G M Kolodny et al.
Cancer research, 43(7), 3101-3103 (1983-07-01)
Sodium hexachloroiridate injected 1 day after i.p. injection of 10(6) mouse ovarian tumor cells prevents the appearance of ascitic tumors in mice. Mice given injections of tumor cells all die at 20 to 30 days after tumor injection. Mice treated
Salah Boussaad et al.
Journal of the American Chemical Society, 130(12), 3780-3787 (2008-03-07)
In an effort to develop sensitive nanoscale devices for chemical and biological sensing, we have examined, using liquid gating, the conductance of semiconducting single-walled carbon nanotube-based field-effect transistors (SWCNT-FETs) in the presence of redox mediators. As examples, redox couples K3Fe(CN)6/K4Fe(CN)6
Nootan Bhattarai et al.
Inorganic chemistry, 51(24), 13303-13311 (2012-11-29)
The aqueous oxidations of glutathione (GSH) by [IrCl(6)](2-), [Fe(bpy)(2)(CN)(2)](+), and [Fe(bpy)(CN)(4)](-) are described. All three reactions are highly susceptible to catalysis by traces of copper ions, but this catalysis can be fully suppressed with suitable chelating agents. The direct oxidation
Z S Farhangrazi et al.
Biochemistry, 34(46), 14970-14974 (1995-11-21)
Horseradish peroxidase (HRP) was oxidized by IrCl6(2-) to a mixture of compounds I and II, the rate of oxidation and the ratio of the mixture being greatly affected by pH (Hayashi & Yamazaki, 1979). Oxidation of HRP by IrCl6(2-) in
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