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Merck
CN

204625

Thallium(I) sulfate

99.99% trace metals basis, solid

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About This Item

Linear Formula:
Tl2SO4
CAS Number:
Molecular Weight:
504.83
UNSPSC Code:
12161600
eCl@ss:
38120904
PubChem Substance ID:
NACRES:
NA.22
EC Number:
231-201-3
MDL number:
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Product Name

Thallium(I) sulfate, 99.99% trace metals basis

SMILES string

[Tl+].[Tl+].[O-]S([O-])(=O)=O

InChI

1S/H2O4S.2Tl/c1-5(2,3)4;;/h(H2,1,2,3,4);;/q;2*+1/p-2

InChI key

YTQVHRVITVLIRD-UHFFFAOYSA-L

assay

99.99% trace metals basis

form

solid

reaction suitability

core: thallium, reagent type: catalyst

mp

632 °C (lit.)

density

6.77 g/mL at 25 °C (lit.)

Quality Level

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General description

Thallium(I) sulfate is mainly used in organic synthesis as an oxidizing agent. It can facilitate the oxidation of various organic compounds, such as alcohols, to corresponding aldehydes or ketones. This reaction is commonly known as the Reformatsky reaction.1 Additionally, thallium sulfate is employed in the preparation of thallium salts for use in analytical chemistry and research applications. It is also utilized in the production of luminous paints, photoelectric cells, and low-melting glasses.

Application

Thallium(I)sulfate is also utilized in:

  • the synthesis of alkylated cyclopentadienes and 7-substitutedbicyclo[2.2.1]heptane derivatives
  • inthe preparation of thallium borate species such as TlBPH43

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 2 - Skin Irrit. 2 - STOT RE 1 Oral

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Methoxymethylation of thallous cyclopentadienide. Simplified preparation of a key intermediate for the synthesis of prostaglandins
Elias J. Corey, Urs Koelliker, and Jorg Neuffer
Journal of the American Chemical Society, 93(6), 1489?1490-1489?1490 (1971)
J P Keogh et al.
Journal of toxicology and environmental health, 43(3), 351-359 (1994-11-01)
Cytotoxicities of metal salts were determined in the intestinal epithelial cell line I-407 in microwell culture plates over 48 h using the widely utilized and accepted neutral red uptake procedure. Rank order cytotoxicities induced by the metal salts (in terms
D Appenroth et al.
Toxicology letters, 122(3), 255-265 (2001-08-08)
Antioxidants of the vitamin E family have protective effects against metal toxicity. We examined the protective effect of racemic LLU-alpha [2,7,8-trimethyl-2-(carboxyethyl)-6-hydroxychroman] a metabolite of gamma-tocopherol, in comparison to the effect of alpha- and gamma-tocopherol in rats treated with sodium dichromate
L Migliore et al.
Environmental and molecular mutagenesis, 34(4), 279-284 (2000-01-05)
The capability of some metal compounds for inducing micronuclei (MN) in human lymphocytes was studied. In this investigation, Al (III), Cd (II), Hg (II), Sb (V), Te (VI), and Tl (I) salts were considered. The FISH (fluorescence in situ hybridization)
Changes in adenosine triphosphate (ATP) concentration and its activity in murine tissue after thallium administration.
M Yoshida et al.
Bulletin of environmental contamination and toxicology, 59(2), 268-273 (1997-08-01)

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