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Merck
CN

204625

Thallium(I) sulfate

99.99% trace metals basis, solid

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About This Item

Linear Formula:
Tl2SO4
CAS Number:
7446-18-6
Molecular Weight:
504.83
UNSPSC Code:
12161600
eCl@ss:
38120904
PubChem Substance ID:
24852283
NACRES:
NA.22
EC Number:
231-201-3
MDL number:
MFCD00011278

Key Documents

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Product Name

Thallium(I) sulfate, 99.99% trace metals basis

SMILES string

[Tl+].[Tl+].[O-]S([O-])(=O)=O

InChI

1S/H2O4S.2Tl/c1-5(2,3)4;;/h(H2,1,2,3,4);;/q;2*+1/p-2

InChI key

YTQVHRVITVLIRD-UHFFFAOYSA-L

assay

99.99% trace metals basis

form

solid

reaction suitability

core: thallium
reagent type: catalyst

mp

632 °C (lit.)

density

6.77 g/mL at 25 °C (lit.)

Quality Level

100

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Application

Thallium(I)sulfate is also utilized in:

  • the synthesis of alkylated cyclopentadienes and 7-substitutedbicyclo[2.2.1]heptane derivatives
  • inthe preparation of thallium borate species such as TlBPH43

General description

Thallium(I) sulfate is mainly used in organic synthesis as an oxidizing agent. It can facilitate the oxidation of various organic compounds, such as alcohols, to corresponding aldehydes or ketones. This reaction is commonly known as the Reformatsky reaction.1 Additionally, thallium sulfate is employed in the preparation of thallium salts for use in analytical chemistry and research applications. It is also utilized in the production of luminous paints, photoelectric cells, and low-melting glasses.

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Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 2 - Skin Irrit. 2 - STOT RE 1 Oral

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP1928
MKCN1778
MKCK9785
MKBW4958V
MKBR3672V

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Methoxymethylation of thallous cyclopentadienide. Simplified preparation of a key intermediate for the synthesis of prostaglandins
Elias J. Corey, Urs Koelliker, and Jorg Neuffer
Journal of the American Chemical Society, 93(6), 1489?1490-1489?1490 (1971)
J P Mulkey et al.
Veterinary and human toxicology, 40(1), 11-14 (1998-02-19)
Thallium is a highly toxic cumulative poison in humans and animals. The use of the metal as a component in ceramic superconductor material (CSM) raised concern about the health risk of CSM to children accidentally swallowing some of the CSM
D Appenroth et al.
Toxicology letters, 122(3), 255-265 (2001-08-08)
Antioxidants of the vitamin E family have protective effects against metal toxicity. We examined the protective effect of racemic LLU-alpha [2,7,8-trimethyl-2-(carboxyethyl)-6-hydroxychroman] a metabolite of gamma-tocopherol, in comparison to the effect of alpha- and gamma-tocopherol in rats treated with sodium dichromate
The pollen tube growth test.
U Kristen et al.
Methods in molecular biology (Clifton, N.J.), 43, 189-198 (1995-01-01)
J T Kielstein et al.
Kidney & blood pressure research, 27(3), 197-199 (2004-07-17)
Guided by the idea of providing a stable electrolyte composition of the dialysate, the late Bernd Tersteegen designed a machine ingeniously combining the advantages of a closed tank hemodialysis system with the efficacy and bacteriological safety of a single-pass system.
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