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Merck
CN

205699

Palladium on carbon

greener alternative

extent of labeling: 10 wt. % loading, matrix activated carbon support, powder

Synonym(s):

Pd/C

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About This Item

Linear Formula:
Pd
Molecular Weight:
106.42
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Palladium on carbon, extent of labeling: 10 wt. % loading, matrix activated carbon support

form

powder

Quality Level

reaction suitability

core: palladium, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

extent of labeling

10 wt. % loading

matrix

activated carbon support

greener alternative category

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Palladium on carbon (Pd/C) (10 wt. % loading, matrix activated carbon support) can be used as a catalyst in the well known reactions like hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; dehydrogenate aromatics and deformylate aldehydes.
It can also be used as:

  • A catalyst for hydrodechlorination of dichlorodifluoromethane (CCl2F2), which is a known greenhouse gas,
  • A catalyst for Heck reactions of aryl halides in ionic liquids
  • An anode catalyst for the fabrication of direct formic acid fuel cells (DFAFC)
  • A cost-effective electrocatalyst for the oxidation of methanol
  • In the catalytic hydrogenation of chemical hydrides for the production of hydrogen
  • A catalyst in Suzuki-Mayaura reaction
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
Catalyst for:
  • Stille reaction
  • Hydrogenation reactions
  • Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions
  • Deoxygenation
  • Oxidation reactions
  • Coupling reactions


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Characterisation of the deactivation of platinum and palladium supported on activated carbon used as hydrodechlorination catalysts
Ordonez S, et al.
Applied Catalysis. B, Environmental, 31(2), 113-122 (2001)
Heterogeneous Heck reaction catalyzed by Pd/C in ionic liquid
Hagiwara H, et al.
Tetrahedron Letters, 42(26), 4349-4351 (2001)
Pd-C powder and thin film catalysts for hydrogen production by hydrolysis of sodium borohydride
Patel N, et al.
International Journal of Hydrogen Energy, 33(1), 287-292 (2008)



Global Trade Item Number

SKUGTIN
205699-50G04061838768063
205699-1G04061838768049
205699-10G04061838768032
205699-250G04061838768056