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Merck
CN

205702

Palladium on alumina

greener alternative

extent of labeling: 1 wt. % loading, (Powder or beads)

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About This Item

Linear Formula:
Pd
PubChem Substance ID:
24852340
UNSPSC Code:
12161600
MDL number:
MFCD03613602

Key Documents

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InChI

1S/Pd

SMILES string

[Pd]

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

form

(Powder or beads)

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

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sustainability

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extent of labeling

1 wt. % loading

mp

1552 °C (lit.)

greener alternative category

Enabling,

Quality Level

100

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General description

Palladium on alumina (Pd/Al2O3) (1 wt % loading, powder) is a widely utilized catalyst that can be prepared by wet impregnation of alumina pellets with palladium chloride. It can also be prepared by flame spray pyrolysis (FSP) by utilizing the precursor solution of aluminum sec-butoxide and palladium acetylacetonate.

Application

Pd/Al2O3 can be used as a catalyst in the enantioselective hydrogenation reaction. It can also be potentially used in the formation of an automotive catalytic converter to improve the air quality of urban environments.

Other Notes

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX9527
MKCP8672
MKCM6378
MKCH0230
MKBX4178V

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Catalytic activity of Pd/Al2O3 toward the combustion of methane
Gao D, et al.
Catalysis Communications, 9(15), 2583-2587 (2008)
Flame spray synthesis of Pd/Al2O3 catalysts and their behavior in enantioselective hydrogenation
Strobel R, et al.
J. Catal., 222(2), 307-314 (2004)
Aqueous bromate reduction by catalytic hydrogenation over Pd/Al2O3 catalysts
Chen H, et al.
Applied Catalysis. B, Environmental, 96(3-4), 307-313 (2010)
Identification of the phytosphingosine metabolic pathway leading to odd-numbered fatty acids
Kondo N, et al.
Nature Communications, 5(1), 1-13 (2014)

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