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About This Item
Linear Formula:
K2PdCl4
CAS Number:
Molecular Weight:
326.43
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-049-3
MDL number:
Assay:
98%
Grade:
synthesis grade
Form:
crystals
Product Name
Potassium tetrachloropalladate(II), 98%
InChI key
LGCKLDWLSVFMGL-UHFFFAOYSA-J
InChI
1S/4ClH.2K.Pd/h4*1H;;;/q;;;;2*+1;+2/p-4
SMILES string
[K+].[K+].Cl[Pd--](Cl)(Cl)Cl
Quality Level
grade
synthesis grade
assay
98%
form
crystals
reaction suitability
core: potassium
mp
105 °C (dec.) (lit.)
density
2.67 g/mL at 25 °C (lit.)
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Application
Potassium tetrachloropalladate(II) can be used:
- As a precursor to synthesize Pd nanoparticles for catalytic degradation of organic pollutants and Pd-GO electrocatalyst in formic acid and ethanol oxidation.
- To synthesize Pd–Pt alloy nanocrystals (NCs) with hollow structures by a galvanic replacement method with uniform Pd octahedral and cubic NCs as sacrificial templates. The hollow NCs exhibited higher ORR activities.
- To synthesize immobilized Pd catalysts, a versatile method involves the layer-by-layer deposition of PAA and PEI-Pd(II) on alumina, followed by the reduction of Pd2+. This approach offers several benefits, including the stabilization of particles through the polyelectrolyte matrix, introduction of selectivity, and a significant reduction in undesired isomerization. Expanding the application of polyelectrolyte films holds promise for further enhancing selectivity in hydrogenation and other reactions.
- To fabricate conductive and porous metal-organic frameworks(MOFs) for gas sensing applications and also to synthesize bimetallic Pd/SnO2 nanoparticles on metal organic framework (MOF) as an electrocatalyst for ethanol oxidation.
- To prepare rigid macrocyclic pincer catalysts possessing polyaromatic ligands with enhanced catalytic activity.
Features and Benefits
Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar. Reacts with bis(dithiolates) to metal-bis(dithiolates) with applications in laser Q-switch materials, optical CD recording media, bar code material and superconductivity.
General description
Potassium tetrachloropalladate(II) is a dark brown crystalline solid widely used as a Pd source in the field of catalysis, nanomaterial synthesis, and electronics.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
Joris Muris et al.
Contact dermatitis, 67(2), 94-100 (2012-04-03)
Exposure to palladium (Pd) may lead to clinical allergic reactions. With frequent nickel (Ni) exposure and cross-reactivity between Ni and Pd at the T cell recognition level, positive Pd reactions on patch testing are surprisingly uncommon. PdCl(2) is often used
L V Tat'ianenko et al.
Voprosy meditsinskoi khimii, 28(6), 126-131 (1982-11-01)
Mechanism of interaction between biologically active substances and membranes as well as and membrane-bound enzymes of two types: mitochondrial monoamine oxidase (MAO) from rat liver tissue and Ca2+, Mg+2-dependent ATPase from sarcoplasmic reticulum (SR) were studied. All the substances studied
A water-based synthesis of octahedral, decahedral, and icosahedral Pd nanocrystals.
Byungkwon Lim et al.
Angewandte Chemie (International ed. in English), 46(48), 9279-9282 (2007-10-31)
V A Tomilets et al.
Farmakologiia i toksikologiia, 44(1), 77-80 (1981-01-01)
A scheme has been devised that makes it possible to assess a specific mechanism of action of any histamine-releasing agent. The scheme suggests a switch off of different stages of histamine secretion--interaction of a histamine liberator with surface cell receptors
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