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Merck
CN

206075

Potassium tetrachloroplatinate(II)

98%

Synonym(s):

Potassium platinum(II) chloride

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About This Item

Linear Formula:
K2PtCl4
CAS Number:
Molecular Weight:
415.09
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-050-9
MDL number:
Assay:
98%
Form:
solid
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Product Name

Potassium tetrachloroplatinate(II), 98%

InChI key

RVRDLMCWUILSAH-UHFFFAOYSA-J

InChI

1S/4ClH.2K.Pt/h4*1H;;;/q;;;;2*+1;+2/p-4

SMILES string

[K+].[K+].Cl[Pt--](Cl)(Cl)Cl

assay

98%

form

solid

reaction suitability

core: potassium

density

3.38 g/mL at 25 °C (lit.)

Quality Level

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Application

Potassium tetrachloroplatinate(II) can be used as:
  • A precursor to synthesize CO-tolerant catalyst for hydrogen-air fuel cells.
  • An active and stable catalyst for selective methane oxidation.
  • As a starting material to synthesize high-performance Pt-based phosphorescent materials for electroluminescent devices.

Features and Benefits

Reacts with bis(dithiolates) to form metal-bis(dithiolates) with applications in laser Q-switch materials, liquid crystals, optical CD recording media, bar code materials and superconductivity. Reacts with capping polymers to form shape-control colloidal platinum nanoparticles for catalysis and photocatalysts.

General description

Potassium tetrachloroplatinate(II) is a ruby-red crystalline solid and can be prepared by reacting potassium hexachloroplatinate(IV) with cuprous chloride. It is mainly used as a reagent and inorganic catalyst in various chemical reactions. Its application includes the synthesis of other platinum compounds, organic transformations, and electroplating of metals. It is also a potential antitumor agent.

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Synthesis of shaped Pt nanoparticles using common anions or small molecules as shape-directing agents: observation of a strong halide or pseudo-halide effect.
Michel JA, et al.
Journal of Materials Chemistry, 3(5), 2012-2018 (2015)
Raj G
Advances in Inorganic Chemistry null
A Solution Phase Synthesis of Dendritic Platinum Nanoelectrocatalysts with the Assistance of Polyoxyethylene Nonylphenyl Ether.
Wang H, et al.
Journal of Inorganic and Organometallic Polymers and Materials, 25(2), 245-250 (2015)
Kyubin Shim et al.
Scientific reports, 9(1), 894-894 (2019-01-31)
Bimetallic nanoparticles (NPs) have aroused interest in various fields because of their synergetic and unique properties. Among those nanoparticles, we strategically approached and synthesized Au@Pt NPs via the sonochemical method with different molar ratios (e.g. 3:7, 5:5, and 7:3) of
The Biological Activity of Zeise's Salt and its Derivatives
Meieranz S, et al.
Angewandte Chemie (International Edition in English), 54(9), 2834-2837 (2015)

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