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Merck
CN

206091

Platinum(II) chloride

98%, powder

Synonym(s):

Platinum dichloride

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About This Item

Linear Formula:
PtCl2
CAS Number:
10025-65-7
Molecular Weight:
265.98
UNSPSC Code:
12161600
eCl@ss:
38191303
PubChem Substance ID:
24852376
NACRES:
NA.22
MDL number:
MFCD00011181

Key Documents

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Product Name

Platinum(II) chloride, 98%

SMILES string

Cl[Pt]Cl

InChI

1S/2ClH.Pt/h2*1H;/q;;+2/p-2

InChI key

CLSUSRZJUQMOHH-UHFFFAOYSA-L

assay

98%

form

powder

reaction suitability

core: platinum, reagent type: catalyst

mp

581 °C (dec.) (lit.)

density

6.05 g/mL at 25 °C

Quality Level

100

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Application

Platinum (II) chloride is a catalyst used for a variety of C-C bond, C-O bond, and C-N bond formation.
Platinum (II) chloride can be used to catalyze the cyclization of 1‐(indole‐2‐yl)‐2,3‐allenols to form polysubstituted carbazoles. It is also used in studies involving metalation of aromatic compounds.

pictograms

Health hazardCorrosion
GHS08,GHS05

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX9189
MKCW4947
MKCS8811
MKCV3817
MKCR2126

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Exclusive 1, 2-Aryl Shift in Platinum (II) Chloride-Catalyzed Cyclization of 1-(Indol-2-yl)-2, 3-allenols
Kong W, et al.
Advanced Synthesis & Catalysis, 354(11-12), 2339-2347 (2012)
Oyamada, J.; Kitamura, J.
Tetrahedron Letters, 46, 3823-3823 (2005)
Exclusive 1, 2-Aryl Shift in Platinum (II) Chloride-Catalyzed Cyclization of 1-(Indol-2-yl)-2, 3-allenols
Kong W, et al.
advanced synthesis and catalysis, 354(11-12), 2339-2347 (2012)
Reactions of tri-tert-butylphosphine with platinum (II) and palladium (II). Facile intramolecular metalation of tri-tert-butylphosphine
Goel, Ram G and Montemayor, Reynaldo
Inorganic Chemistry, 16(9), 2183-2186 (1977)
A New σ-Bonded Complex Formation between 2-Vinylpyridine and Palladium (II) or Platinum (II) Chloride
Kasahara, Akira and Tanaka, Keiko and Izumi, Taeko
Bulletin of the Chemical Society of Japan, 42(6), 1702-1704 (1969)
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