Skip to Content
Merck
CN

208353

Molybdenum(V) chloride

95%

Synonym(s):

Molybdenum pentachloride, Pentachloromolybdenum

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Linear Formula:
MoCl5
CAS Number:
Molecular Weight:
273.21
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
95%
Form:
powder
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist


Quality Segment

vapor pressure

1.75 mmHg ( 25 °C), 131 mmHg ( 250 °C)

assay

95%

form

powder

reaction suitability

core: molybdenum, reagent type: catalyst

impurities

<0.5% insoluble matter

bp

268 °C (lit.)

mp

194 °C (lit.)

density

2.928 g/mL at 25 °C (lit.)

SMILES string

Cl[Mo](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

InChI key

GICWIDZXWJGTCI-UHFFFAOYSA-I

General description

Molybdenum(V)chloride is a Lewis acid widely used as a catalyst and reagent in many organicreactions. It can be prepared by direct chlorination of molybdenum metal or byrefluxing thionyl chloride and MoO3.

Application

Molybdenum(V) chloride can be used as an efficient catalyst for:
  • Condensation of nitrobenzene with alcohols and C-C coupling of alkenyllithium reagents.
  • Direct amidation of benzylic alcohols with sulfonamides and carbamates.
It can be used for the chlorination of alkyl halides, alkenes, and alkynes.

It can also be used as aprecursor to synthesize alumina/molybdenum nanocomposites and methylenemolybdenumreagents for chemoselective carbonyl alkenation.


Still not finding the right product?

Explore all of our products under Molybdenum(V) chloride


Pictograms

Health hazardCorrosion

Signal Word

Danger

Hazard Codes

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable



Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library