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About This Item
Linear Formula:
MoCl5
CAS Number:
Molecular Weight:
273.21
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
95%
Form:
powder
Quality Segment
vapor pressure
1.75 mmHg ( 25 °C), 131 mmHg ( 250 °C)
assay
95%
form
powder
reaction suitability
core: molybdenum, reagent type: catalyst
impurities
<0.5% insoluble matter
bp
268 °C (lit.)
mp
194 °C (lit.)
density
2.928 g/mL at 25 °C (lit.)
SMILES string
Cl[Mo](Cl)(Cl)(Cl)Cl
InChI
1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5
InChI key
GICWIDZXWJGTCI-UHFFFAOYSA-I
General description
Molybdenum(V)chloride is a Lewis acid widely used as a catalyst and reagent in many organicreactions. It can be prepared by direct chlorination of molybdenum metal or byrefluxing thionyl chloride and MoO3.
Application
Molybdenum(V) chloride can be used as an efficient catalyst for:
It can also be used as aprecursor to synthesize alumina/molybdenum nanocomposites and methylenemolybdenumreagents for chemoselective carbonyl alkenation.
- Condensation of nitrobenzene with alcohols and C-C coupling of alkenyllithium reagents.
- Direct amidation of benzylic alcohols with sulfonamides and carbamates.
It can also be used as aprecursor to synthesize alumina/molybdenum nanocomposites and methylenemolybdenumreagents for chemoselective carbonyl alkenation.
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Signal Word
Danger
Hazard Codes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
Precautionary Statements
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