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Merck
CN

208361

Silver tetrafluoroborate

98%

Synonym(s):

Silver borofluoride

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About This Item

Linear Formula:
AgBF4
CAS Number:
Molecular Weight:
194.67
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
237-956-5
MDL number:
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Quality Level

assay

98%

reaction suitability

core: silver, reagent type: catalyst

mp

70-73 °C (lit.)

SMILES string

[Ag+].F[B-](F)(F)F

InChI

1S/Ag.BF4/c;2-1(3,4)5/q+1;-1

InChI key

CCAVYRRHZLAMDJ-UHFFFAOYSA-N

General description

Silver tetrafluoroborate (AgBF4) is used as a Lewis acid in organic synthesis. It is known to have a high affinity towards organic halides. It is employed in organic reactions like activation of acyl chlorides, nucleophilic substitution, rearrangement, cycloaddition, cyclization, ring expansion and oxidation.

Application

Displaces chloride from precious metal complexes used in the oxidation of alcohols by persulfate.
Provides a silver-ion template for improved macrolatamization of a linear dipeptide.


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品

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Articles

Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.


Silver tetrafluoroborate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2005)
Silver tetrafluoroborate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2005)
Synlett, 1901-1901 (2007)



Global Trade Item Number

SKUGTIN
208361-10G04061838769725
208361-1G04061838769732
208361-50G04061833545164