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212911

Palladium hydroxide on carbon

extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support, solid

Synonym(s):

Pd(OH)2/C, Pearlman’s catalyst

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About This Item

Empirical Formula (Hill Notation):
H2O2Pd
CAS Number:
12135-22-7
Molecular Weight:
140.43
NACRES:
NA.22
PubChem Substance ID:
24852754
UNSPSC Code:
12161600
EC Number:
235-219-2
MDL number:
MFCD00064599
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Product Name

Palladium hydroxide on carbon, extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support

form

powder

Quality Segment

200

contains

≤50% water

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

extent of labeling

20 wt. % loading (dry basis)

matrix

carbon, wet support

SMILES string

O[Pd]O

InChI

1S/2H2O.Pd/h2*1H2;/q;;+2/p-2

InChI key

NXJCBFBQEVOTOW-UHFFFAOYSA-L

Application

Addition of Pd/C to Pd(OH)2/C improves the efficiency of N- or O-debenzylation.
Effectively catalyzes the direct arylation reactions of aryl iodides and bromides in both intra- and intermolecular processes.
Particularly active for hydrogenolysis of benzyl-nitrogen bonds, and has proven successful even where other palladium-on-carbon catalysts have failed.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

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Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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