Skip to Content
Merck
CN

Key Documents

View All Documentation

213217

Lithium amide

greener alternative

powder, 95%

Synonym(s):

Aminolithium, Lithamide

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Linear Formula:
LiNH2
CAS Number:
7782-89-0
Molecular Weight:
22.96
NACRES:
NA.22
PubChem Substance ID:
24852671
UNSPSC Code:
12352301
EC Number:
231-968-4
MDL number:
MFCD00011093
Assay:
95%
Form:
powder
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Quality Level

200

assay

95%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

380-400 °C

density

1.178 g/mL at 25 °C (lit.)

greener alternative category

Enabling,

SMILES string

[Li].CN

InChI

1S/Li.H2N/h;1H2/q+1;-1

InChI key

AFRJJFRNGGLMDW-UHFFFAOYSA-N

General description

Lithium amide (LiNH2) is an amide of an alkali metal with lithium atoms having larger positive charges than hydrogen atoms. It is a moisture-sensitive molecule that converts to LiOH and NH3 on reaction with H2O. LiNH2 is majorly used in hydrogen storage applications.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Reagent for synthesis of:
Antiinflamatory and preoresolving protectin D1
Chemotype dipeptidyl peptidase IV inhibitors
Sterically congested triarylamines
Dyes displaying large Stokes shifts
GM1 ganglioside derivatives

Reagent for cross-coupling of aryl chlorides and amines

Still not finding the right product?

Explore all of our products under Lithium amide

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Self-heat. 1 - Skin Corr. 1B - Water-react. 2

supp_hazards

EUH014

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

Regulatory Information

监管及禁止进口产品

This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKDB0988
MKCX9775
MKCT7011
MKCT5596
MKCS5904

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

Complex Hydrides: New Solid-state Conductors

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

Rylan J Lundgren et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(6), 1983-1991 (2009-12-22)
The syntheses of 2-(di-tert-butylphosphino)-N,N-dimethylaniline (L1, 71%) and 2-(di-1-adamantylphosphino)-N,N-dimethylaniline (L2, 74 %), and their application in Buchwald-Hartwig amination, are reported. In combination with [Pd(allyl)Cl](2) or [Pd(cinnamyl)Cl](2), these structurally simple and air-stable P,N ligands enable the cross-coupling of aryl and heteroaryl chlorides
G. Bordeau, et al.,
Tetrahedron Letters, 51, 4429-4432 (2010)
N. Ogawa and Y. Kobayashi,
Tetrahedron Letters, 52, 3001-3004 (2011)
View All Related Papers

Global Trade Item Number

SKUGTIN
213217-5G04061833545232
213217-100G04061838347169
213217-500G04061833545225