213438
Potassium triethylborohydride solution
1.0 M in THF
Synonym(s):
Potassium hydrotriethylborate, Potassium triethylhydridoborate
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About This Item
Linear Formula:
KB(C2H5)3H
CAS Number:
Molecular Weight:
138.10
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352000
MDL number:
Form:
liquid
form
liquid
Quality Segment
reaction suitability
reagent type: reductant
concentration
1.0 M in THF
density
0.902 g/mL at 25 °C
SMILES string
[K+].[H][B-](CC)(CC)CC
InChI
1S/C6H16B.K/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1
InChI key
MFRDRDKPANBWOI-UHFFFAOYSA-N
Application
- Reducing agent for synthesis of PtNi intermetallic nanoparticle catalysts with electrocatalytic activity
- Reducing agent for preparation of vanadium nanoparticles (~7 nm) stabilized on activated carbon
Reagent for:
- Preparation of lithium, sodium, and potassium boron monohydride complexes with tetramethylethylenediamine and pentamethyldiethylenetriamine
- Dehydrogenation reactions
- Tandem nucleophilic addition/C-C bond cleaving fragmentation reactions with cyclic vinylogous acyl triflates
- Preparation of coordinatively unsaturated pseudotetrahedral iron(II) precursors as precatalysts for the room-temperature hydrogenation of unsaturated hydrocarbons
- Substitution reactions
Signal Word
Danger
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
Flash Point (°F)
1.4 °F - closed cup
Flash Point (°C)
-17 °C - closed cup
Hazard Codes
Precautionary Statements
Target Organs
Central nervous system, Respiratory system
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
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