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Merck
CN

213497

2-Hydroxycarbazole

97%

Synonym(s):

2-Carbazolol

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About This Item

Empirical Formula (Hill Notation):
C12H9NO
CAS Number:
Molecular Weight:
183.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-699-7
Beilstein/REAXYS Number:
135859
MDL number:
Assay:
97%
Form:
solid
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Quality Segment

assay

97%

form

solid

mp

270-273 °C (lit.)

SMILES string

Oc1ccc2c(c1)[nH]c3ccccc23

InChI

1S/C12H9NO/c14-8-5-6-10-9-3-1-2-4-11(9)13-12(10)7-8/h1-7,13-14H

InChI key

GWPGDZPXOZATKL-UHFFFAOYSA-N

General description

2-Hydroxycarbazole is a compound structurally related to the Ca2+-mobilizing marine toxin, 9-methyl-7-bromoeudistomin. Room temperature electronic absorption and fluorescence spectra of 2-hydroxycarbazole has been studied in concentrated aqueous potassium hydroxide solutions. It undergoes chemoselective N-alkylation using NaH as a base in a THF-DMF solvent system.

Application

2-Hydroxycarbazole was used in the synthesis of isochromene fused carbazol, (4aS,13bR)-2,5,5-trimethyl-3,4,4a,5,8,13b-hexahydroisochromeno[3,4-b]carbazole.


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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