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Merck
CN

213950

Vinyltrimethylsilane

97%

Synonym(s):

Trimethyl(vinyl)silane, (Trimethylsilyl)ethylene, Ethenyltrimethylsilane

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About This Item

Linear Formula:
(CH3)3SiCHCH2
CAS Number:
Molecular Weight:
100.23
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-042-9
Beilstein/REAXYS Number:
956572
MDL number:
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Product Name

Vinyltrimethylsilane, 97%

InChI key

GCSJLQSCSDMKTP-UHFFFAOYSA-N

InChI

1S/C5H12Si/c1-5-6(2,3)4/h5H,1H2,2-4H3

SMILES string

C[Si](C)(C)C=C

vapor pressure

4.44 psi ( 20 °C)

assay

97%

form

liquid

impurities

<3% tetrahydrofuran

refractive index

n20/D 1.391 (lit.)

bp

55 °C (lit.)

density

0.684 g/mL at 25 °C (lit.)

Quality Level

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Application

Used for the preparation of trimethylsilylethyl sulfoxides which in the presence of fluoride ion generate sulfenate nucleophiles.

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Danger

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-11.2 °F

flash_point_c

-24 °C

ppe

Eyeshields, Faceshields, Gloves

Regulatory Information

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Synthesis, 1315-1315 (2007)
J. Chem. Soc. Perkin Trans. II, 1129-1129 (1993)
Seco-steroids. I. 15,16-Secoprogesterone.
N S Crossley
Journal of the Chemical Society. Perkin transactions 1, 13, 2491-2495 (1971-01-01)
J. Mol. Catal., 90, 125-125 (1994)

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