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Merck
CN

213950

Vinyltrimethylsilane

97%

Synonym(s):

Trimethyl(vinyl)silane, (Trimethylsilyl)ethylene, Ethenyltrimethylsilane

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About This Item

Linear Formula:
(CH3)3SiCHCH2
CAS Number:
Molecular Weight:
100.23
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-042-9
Beilstein/REAXYS Number:
956572
MDL number:
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vapor pressure

4.44 psi ( 20 °C)

Quality Level

assay

97%

form

liquid

impurities

<3% tetrahydrofuran

refractive index

n20/D 1.391 (lit.)

bp

55 °C (lit.)

density

0.684 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)C=C

InChI

1S/C5H12Si/c1-5-6(2,3)4/h5H,1H2,2-4H3

InChI key

GCSJLQSCSDMKTP-UHFFFAOYSA-N

Application

Used for the preparation of trimethylsilylethyl sulfoxides which in the presence of fluoride ion generate sulfenate nucleophiles.


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signalword

Danger

supp_hazards

Storage Class

3 - Flammable liquids

flash_point_f

-11.2 °F

flash_point_c

-24 °C

ppe

Eyeshields, Faceshields, Gloves

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2

Regulatory Information

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J. Mol. Catal., 90, 125-125 (1994)
Synthesis, 1315-1315 (2007)
J. Chem. Soc. Perkin Trans. II, 1129-1129 (1993)



Global Trade Item Number

SKUGTIN
213950-100G04061838347183
213950-25G04061838773012
213950-5G04061837909887