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Merck
CN

219401

2-Fluoroiodobenzene

99%, contains copper as stabilizer

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About This Item

Linear Formula:
FC6H4I
CAS Number:
348-52-7
Molecular Weight:
222.00
NACRES:
NA.22
PubChem Substance ID:
24853126
UNSPSC Code:
12352100
EC Number:
206-477-3
MDL number:
MFCD00001031

Key Documents

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Product Name

2-Fluoroiodobenzene, 99%, contains copper as stabilizer

InChI key

TYHUGKGZNOULKD-UHFFFAOYSA-N

InChI

1S/C6H4FI/c7-5-3-1-2-4-6(5)8/h1-4H

SMILES string

Fc1ccccc1I

assay

99%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.59 (lit.)

bp

188-189 °C (lit.)

mp

−41-−40 °C (lit.)

density

1.903 g/mL at 25 °C (lit.)

functional group

fluoro
iodo

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Application

2-Fluoroiodobenzene was used in the synthesis of:
  • bridged biphenyl compounds, 1-fluoro-8-methylbiphenylene and 4-fluoro-5-methylfluorene
  • 2-acetyl-7-iodo-1-benzothiophene
  • chiral o-phosphanophenyl sulfoxides

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 2

flash_point_f

159.8 °F - closed cup

flash_point_c

71 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCCB3025
BCBZ3050
BCBV2201
BCBS9173V
BCBP2338V

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Pierre-Yves Michellys et al.
Bioorganic & medicinal chemistry letters, 14(6), 1593-1598 (2004-03-10)
The synthesis and in vitro characterization of novel RXR-selective ligands possessing various substituted 1-benzofuran or 1-benzothiophene moieties are described.
New chiral sulfoxide ligands possessing a phosphano or phosphanoamino functionality in palladium-catalyzed asymmetric allylic nucleophilic substitution reactions.
Hiroi K, et al.
Tetrahedron, 56(27), 4701-4710 (2000)
Long-range proton-fluorine spin-spin coupling in bridged biphenyls. Compelling evidence for a" through-space"(" direct") mechanism.
Gribble GW and Douglas Jr JR.
Journal of the American Chemical Society, 92(19), 5764-5765 (1970)

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