221058
Tris(dimethylamino)methane
97%
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About This Item
Linear Formula:
[(CH3)2N]3CH
CAS Number:
Molecular Weight:
145.25
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
227-284-0
Beilstein/REAXYS Number:
1901162
MDL number:
Product Name
Tris(dimethylamino)methane, 97%
InChI key
MUMVIYLVHVCYGI-UHFFFAOYSA-N
InChI
1S/C7H19N3/c1-8(2)7(9(3)4)10(5)6/h7H,1-6H3
SMILES string
CN(C)C(N(C)C)N(C)C
assay
97%
form
liquid
refractive index
n20/D 1.436 (lit.)
bp
42-43 °C/12 mmHg (lit.)
density
0.838 g/mL at 20 °C (lit.)
functional group
amine
storage temp.
2-8°C
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Application
Tris(dimethylamino)methane was used:
- to prepare the phosphoramidite derivative of the new nucleoside analog
- as reagent for the introduction of the dimethylaminoethylidene group
- in ring-opening (RO) polymerization of lactide
General description
NMR spectra and their temperature-dependence has been reported for tris(dimethylamino)methane. Tris(dimethylamino)methane reacts with crowded α-(o-nitrophenyl) ketone to yield tetrahydroquinoline derivative.
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
51.8 °F - closed cup
flash_point_c
11 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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Find documentation for the products that you have recently purchased in the Document Library.
yDNA: a new geometry for size-expanded base pairs.
Haige Lu et al.
Angewandte Chemie (International ed. in English), 43(43), 5834-5836 (2004-11-04)
Advanced Synthesis & Catalysis, 346, 1081-1081 (2004)
Sci. Synth., 22, 795-795 (2005)
Conformational Dynamics of Triple Rotors: Tris (dimethylamino) methane, Triisopropylamine, and Related Molecules1.
Anderson JE, et al.
The Journal of Organic Chemistry, 61(4), 1290-1296 (1996)
Tetrahedron, 45, 6631-6631 (1989)
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