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Merck
CN

221759

Ammonium cerium(IV) sulfate dihydrate

Synonym(s):

Ceric ammonium sulfate, Cerium(IV) ammonium sulfate

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About This Item

Linear Formula:
Ce(NH4)4(SO4)4 · 2H2O
CAS Number:
Molecular Weight:
632.55
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
≥94.0% (with KMnO4, redox titration)
Form:
(Powder or Crystals or Chunks)
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assay

≥94.0% (with KMnO4, redox titration)

Quality Segment

form

(Powder or Crystals or Chunks)

composition

Ce(IV), ≥20%

reaction suitability

reagent type: catalyst

mp

130 °C (lit.)

SMILES string

N.N.N.N.O.O.[Ce+4].OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O

InChI

1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;4*1-5(2,3)4;;/h;4*1H3;4*(H2,1,2,3,4);2*1H2/q+4;;;;;;;;;;/p-4

InChI key

VCNAMBGKEDPVGQ-UHFFFAOYSA-J

Application

The product may be used to initiate the radical polymerization of pectin-poly(ethylene glycol) methacrylate (PEGMA) supracmolecular hydrogels. Ammonium cerium sulphate impregnated starch may be carbonized to form cerium dispersed carbon (CeDC) sorbent used for the extraction of excess fluoride in drinking water.


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Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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