223298
N-(Trimethylsilyl)acetamide
95%
Synonym(s):
TMS acetamide
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About This Item
Linear Formula:
CH3CONHSi(CH3)3
CAS Number:
Molecular Weight:
131.25
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
236-565-7
Beilstein/REAXYS Number:
741928
MDL number:
Assay:
95%
Form:
solid
Product Name
N-(Trimethylsilyl)acetamide, 95%
InChI key
LWFWUJCJKPUZLV-UHFFFAOYSA-N
InChI
1S/C5H13NOSi/c1-5(7)6-8(2,3)4/h1-4H3,(H,6,7)
SMILES string
CC(=O)N[Si](C)(C)C
assay
95%
form
solid
bp
84 °C/18 mmHg (lit.)
mp
46-49 °C (lit.)
Quality Level
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General description
The efficiency of N-(Trimethylsilyl)acetamide (TMS acetamide) as allyl group scavenger and its compatibility with Fluorenylmethyloxycarbonyl chloride (Fmoc) protecting groups were studied.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
158.0 °F
flash_point_c
70 °C
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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New allyl group acceptors for palladium catalyzed removal of allylic protections and transacylation of allyl carbamates.
Tetrahedron Letters, 36(32), 5741-5744 (1995)
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