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223298

N-(Trimethylsilyl)acetamide

Name: <I>N</I>-(Trimethylsilyl)acetamide
Brand: ALDRICH

95%

Synonym(s):

TMS acetamide

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About This Item

Linear Formula:

CH₃CONHSi(CH₃)₃

CAS Number:

13435-12-6

Molecular Weight:

131.25

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24853373

EC Number:

236-565-7

Beilstein/REAXYS Number:

741928

MDL number:

MFCD00008671

Assay:

95%

Form:

solid

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Properties

assay

95%

form

solid

bp

84 °C/18 mmHg (lit.)

mp

46-49 °C (lit.)

SMILES string

CC(=O)N[Si](C)(C)C

InChI

1S/C5H13NOSi/c1-5(7)6-8(2,3)4/h1-4H3,(H,6,7)

InChI key

LWFWUJCJKPUZLV-UHFFFAOYSA-N

Description

General description

The efficiency of N-(Trimethylsilyl)acetamide (TMS acetamide) as allyl group scavenger and its compatibility with Fluorenylmethyloxycarbonyl chloride (Fmoc) protecting groups were studied.

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pictograms

GHS07

signalword

Warning

hcodes

H315,H319

pcodes

P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

158.0 °F

flash_point_c

70 °C

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number

0000463373

0000281415

0000196692

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New allyl group acceptors for palladium catalyzed removal of allylic protections and transacylation of allyl carbamates.

Tetrahedron Letters, 36(32), 5741-5744 (1995)

Global Trade Item Number

SKU	GTIN
223298-25G	04061838778277