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Merck
CN

223689

Bis(benzonitrile)palladium(II) chloride

95%, powder

Sustainability features

Synonym(s):

Benzonitrile, palladium complex, Bis(benzonitrile)dichloropalladium(II), Bis(benzonitrile)palladium(II) chloride, Bis(phenylnitrile)dichloropalladium, Dibenzonitrilepalladium dichloride, Dichlorobis(benzonitrile)palladium, Dichlorobis(benzonitrile)palladium(II), Dichlorobis(phenyl cyanide)palladium, Palladium dichloride bis(benzonitrile), Palladium(II) chloride bis(benzonitrile) complex

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About This Item

Linear Formula:
(C6H5CN)2PdCl2
CAS Number:
Molecular Weight:
383.57
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
238-085-3
MDL number:
Beilstein/REAXYS Number:
3981730
eCl@ss:
32150313
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Product Name

Bis(benzonitrile)palladium(II) chloride, 95%

Quality Segment

assay

95%

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: inorganic catalyst

sustainability

Sustainability features

mp

131 °C (lit.)

greener alternative category

SMILES string

Cl[Pd]Cl.N#Cc1ccccc1.N#Cc2ccccc2

InChI

1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

WXNOJTUTEXAZLD-UHFFFAOYSA-L

General description

Bis(benzonitrile)palladium(II) chloride is a coordination compound used as a catalyst in the Suzuki Cross-Coupling reaction.


This product aligns with one or more of the 12 Principles of Green Chemistry Find details here.

Application

Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:
  • For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
  • In cross-coupling reactions and α-O-glycosidation.

Formal anti-Markovnikov hydroamination of terminal olefins


Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Gloves, type N95 (US)



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