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Merck
CN

223816

Lithium iodide hydrate

98%, solid

Synonym(s):

Lithium iodide (LiI), hydrate

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About This Item

Linear Formula:
LiI · xH2O
CAS Number:
Molecular Weight:
133.85 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
233-822-5
MDL number:
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Product Name

Lithium iodide hydrate, 98%

Quality Level

assay

98%

form

solid

composition

Degree of hydration, 1.5-3

reaction suitability

core: lithium, reagent type: catalyst

mp

73 °C (lit.)

density

3.48 g/mL at 25 °C (lit.)

SMILES string

[Li+].[I-].[H]O[H]

InChI

1S/HI.Li.H2O/h1H;;1H2/q;+1;/p-1

InChI key

WAZWGFFJLSIDMX-UHFFFAOYSA-M

Application

Reagent for ester cleavage and decarboxylation; C-C bond forming reactions; used as source of nucleophilic iodide; used as mild Lewis acid; epoxide opening; used as an additive for organometallic-mediated transformations.


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Articles

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.


Bennasar, M.-L.; Jimenez, J.-M.
Tetrahedron Letters, 37, 7653-7653 (1996)
Srilakshmi Krishnaveni, N.; Surendra, K. et al.
Synthesis, 4, 501-501 (2004)
Bajwa, J. S.; Anderson, R. C.
Tetrahedron Letters, 32, 3021-3021 (1991)



Global Trade Item Number

SKUGTIN
223816-500G04061835517848
223816-100G04061838778710