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Merck
CN

224383

Isopropylmagnesium chloride solution

2.0 M in diethyl ether

Synonym(s):

Chloro 1-methylethyl magnesium, Chloroisopropylmagnesium, Isopropylmagnesium chloride, iPrMgCl

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About This Item

Linear Formula:
(CH3)2CHMgCl
CAS Number:
1068-55-9
Molecular Weight:
102.85
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24853433
MDL number:
MFCD00000466
Beilstein/REAXYS Number:
4124221

Key Documents

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InChI

1S/C3H7.ClH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1

SMILES string

CC(C)[Mg]Cl

InChI key

GPIBKUJXKCEZOH-UHFFFAOYSA-M

reaction suitability

reaction type: Grignard Reaction

concentration

2.0 M in diethyl ether

density

0.834 g/mL at 25 °C

Quality Level

100

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Related Categories

signalword

Danger

target_organs

Central nervous system

supp_hazards

EUH014,EUH019

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

-40.0 °F - closed cup

flash_point_c

-40 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBT4805
SHBR5155
SHBS2421
SHBM6915
SHBC6420V

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Well-controlled synthesis of block copolythiophenes.
Ohshimizu K and Ueda M.
Macromolecules, 41(14), 5289-5294 (2008)
The first example of ?-chloromagnesio ?-lactones: their generation from ?-tolylsulfinyl ?-lactones with isopropylmagnesium chloride, stability, and reaction with electrophiles.
Sugiyama S, et al.
Tetrahedron Letters, 47(49), 8771-8775 (2006)
Synthesis of Poly (3-hexylthiophene) with a Narrower Polydispersity.
Miyakoshi R, et al.
Macromolecular Rapid Communications, 25(19), 1663-1666 (2004)
Preparation of amides mediated by isopropylmagnesium chloride under continuous flow conditions.
Mu?oz JM, et al.
Green Chemistry, 14(5), 1335-1341 (2012)

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