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225495

Disodium tetracarbonylferrate dioxane complex

Synonym(s):

Collman’s Reagent

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About This Item

Linear Formula:
Na2Fe(CO)4 · 1.5C4H8O2
CAS Number:
59733-73-2
Molecular Weight:
346.02
NACRES:
NA.22
PubChem Substance ID:
329752324
UNSPSC Code:
12161600
EC Number:
261-892-7
MDL number:
MFCD02091641
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reaction suitability

core: iron, reagent type: catalyst

SMILES string

[Fe--].[Fe--].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Na]C#[O+].[Na]C#[O+].[Na]C#[O+].[Na]C#[O+].C1COCCO1.C2COCCO2.C3COCCO3

InChI

1S/3C4H8O2.8CO.2Fe.4Na/c3*1-2-6-4-3-5-1;8*1-2;;;;;;/h3*1-4H2;;;;;;;;;;;;;;/q;;;;;;;4*+1;2*-2;;;;

InChI key

XEXTUUGKJXEJOB-UHFFFAOYSA-N

Application

Carbonylating agent for halides to form aldehydes andketones; hydroacylates Michael acceptors; also used as reducing agent; catalyst for dismutation of aromatic aldehydesto esters

signalword

Danger

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges

Hazard Classifications

Acute Tox. 3 Inhalation - Carc. 2 - Pyr. Sol. 1 - Water-react. 2

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBJ5084
SHBG5752V
SHBD5485V
27596JKV
27596JK

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Inorganic Chemistry, 20, 645-645 (1981)
Accounts of Chemical Research, 8, 342-342 (1975)
Aldrichimica Acta, 19, 69-69 (1986)
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Global Trade Item Number

SKUGTIN
225495-10G04061833545379