225495
四羰基铁酸二钠合二噁烷
别名:
Collman 试剂
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关于此项目
线性分子式:
Na2Fe(CO)4 · 1.5C4H8O2
化学文摘社编号:
分子量:
346.02
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
261-892-7
MDL number:
reaction suitability
core: iron, reagent type: catalyst
SMILES string
[Fe--].[Fe--].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Na]C#[O+].[Na]C#[O+].[Na]C#[O+].[Na]C#[O+].C1COCCO1.C2COCCO2.C3COCCO3
InChI
1S/3C4H8O2.8CO.2Fe.4Na/c3*1-2-6-4-3-5-1;8*1-2;;;;;;/h3*1-4H2;;;;;;;;;;;;;;/q;;;;;;;4*+1;2*-2;;;;
InChI key
XEXTUUGKJXEJOB-UHFFFAOYSA-N
Application
Carbonylating agent for halides to form aldehydes andketones; hydroacylates Michael acceptors; also used as reducing agent; catalyst for dismutation of aromatic aldehydesto esters
signalword
Danger
hcodes
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges
Hazard Classifications
Acute Tox. 3 Inhalation - Carc. 2 - Pyr. Sol. 1 - Water-react. 2