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Merck
CN

225657

Bis(acetonitrile)dichloropalladium(II)

greener alternative

99%, powder

Synonym(s):

Palladium(II) chloride diacetonitrile complex

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About This Item

Linear Formula:
PdCl2 · (CH3CN)2
CAS Number:
Molecular Weight:
259.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
238-637-3
MDL number:
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Product Name

Bis(acetonitrile)dichloropalladium(II), 99%

InChI key

RBYGDVHOECIAFC-UHFFFAOYSA-L

InChI

1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2

SMILES string

CC#N.CC#N.Cl[Pd]Cl

assay

99%

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

greener alternative product characteristics

Catalysis
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Quality Level

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Application

Catalyst used in an ether-directed aza-Claisen rearrangement.

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

pictograms

Skull and crossbones

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Find documentation for the products that you have recently purchased in the Document Library.

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Larsen, C. H.; Buchwald, S. L. et al.
Synthesis, 2941-2941 (2006)
Murata, M.; Shimazaki, R.; et al.
Synthesis, 2231-2231 (2001)
Horibe, H.; Kazuta, K.
Synlett, 2047-2047 (2003)
Hosokawa, T.; Takano, M.; et al.
Tetrahedron Letters, 33, 6643-6643 (1992)
Stille, J. K.; Groh, L.
Journal of the American Chemical Society, 109, 813-813 (1987)

Articles

A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.

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