Key Documents

View All Documentation

226289

N,N-Dimethyltrimethylsilylamine

Name: <I>N,N</I>-Dimethyltrimethylsilylamine
Brand: ALDRICH

97%

Synonym(s):

(Dimethylamino)trimethylsilane, N-(Trimethylsilyl)dimethylamine, TMSDMA

Select a Size

Change View

About This Item

Linear Formula:

(CH₃)₃SiN(CH₃)₂

CAS Number:

2083-91-2

Molecular Weight:

117.26

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24853554

EC Number:

218-222-3

Beilstein/REAXYS Number:

1731861

MDL number:

MFCD00008297

Assay:

97%

Form:

liquid

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

Quality Segment

200

assay

97%

form

liquid

refractive index

n20/D 1.397 (lit.)

bp

84 °C (lit.)

density

0.732 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CN(C)[Si](C)(C)C

InChI

1S/C5H15NSi/c1-6(2)7(3,4)5/h1-5H3

InChI key

KAHVZNKZQFSBFW-UHFFFAOYSA-N

Description

Application

N,N-Dimethyltrimethylsilylamine can be used as a reactant to prepare:

Trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct, which is used as an efficient reagent for nucleophilic trifluoromethylation of carbonyl and the imine group.
(Dimethylamino)sulfur trifluoride (Me-DAST), which is employed as a deoxofluorinating agent for the conversion of aliphatic alcohols into their corresponding fluorides.
Nucleoside phosphoramidites by reacting with alkyloxy (or aryloxy)-triazolylphosphine and deoxynucleoside.

It can also be used as a silylating agent in chemical synthesis.

pictograms

GHS02,GHS05

signalword

Danger

hcodes

H225,H260,H314

pcodes

P210 - P223 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

10.4 °F - closed cup

flash_point_c

-12 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react. 1

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library