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Merck
CN

227307

Sodium triethylborohydride solution

1.0 M in toluene

Synonym(s):

Sodium triethylborate, Sodium triethylhydridoborate, Sodium triethylhydroborate

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About This Item

Linear Formula:
(C2H5)3NaBH
CAS Number:
Molecular Weight:
121.99
UNSPSC Code:
12352000
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4151241
Form:
liquid
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form

liquid

Quality Segment

reaction suitability

reagent type: reductant

concentration

1.0 M in toluene

density

0.866 g/mL at 25 °C

SMILES string

[Na+].[H][B-](CC)(CC)CC

InChI

1S/C6H16B.Na/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1

InChI key

YDTZLEUIYNMRLQ-UHFFFAOYSA-N

Application

Reactant for:
  • Preparation of alcohols by hydrogenation of ketones catalyzed by an iron pincer complex
  • Preparation of alkali metal boron monohydride complexes
  • Coordinative substitution reactions
  • Ligand exchange reactions

  • Hydridic reagent


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Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

44.6 °F - closed cup

flash_point_c

7 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react. 2



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