227722
Silver hexafluorophosphate
98%, solid
Synonym(s):
Silver(I) hexafluorophosphate
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About This Item
Linear Formula:
AgPF6
CAS Number:
Molecular Weight:
252.83
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
247-428-6
MDL number:
Product Name
Silver hexafluorophosphate, 98%
Quality Level
assay
98%
form
solid
reaction suitability
core: silver, reagent type: catalyst
mp
102 °C (dec.) (lit.)
SMILES string
[Ag+].F[P-](F)(F)(F)(F)F
InChI
1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1
InChI key
SCQBROMTFBBDHF-UHFFFAOYSA-N
General description
Silver hexafluorophosphate can be used as a catalyst for the sulfimidation, hydrogenation of aldehydes to alcohols, and hydroacyloxylation of alkynes with carboxylic acids.
Application
Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials. Preparation of supramolecular networks of Ag(I) complexes.
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Articles
Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.
Gold (I)-catalyzed addition of carboxylic acids to alkynes
Chary B, et al.
The Journal of Organic Chemistry, 75, 7928-7931 (2010)
Silver-Catalyzed Hydrogenation of Aldehydes in Water
Jia Z, et al.
Angewandte Chemie (International Edition in English), 52, 11871-11874 (2013)
Journal of Organometallic Chemistry, 692, 4093-4093 (2007)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 227722-10G | 04061838780881 |
| 227722-1G | 04061838780898 |