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227803

(−)-Diisopropyl D-tartrate

Name: (−)-Diisopropyl <SC>D</SC>-tartrate
Brand: ALDRICH

98%

Synonym(s):

D-(−)-Tartaric acid diisopropyl ester

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About This Item

Linear Formula:

[-CH(OH)CO₂CH(CH₃)₂]₂

CAS Number:

62961-64-2

Molecular Weight:

234.25

UNSPSC Code:

12352108

NACRES:

NA.22

PubChem Substance ID:

24853655

EC Number:

263-771-4

Beilstein/REAXYS Number:

5265431

MDL number:

MFCD00008876

Assay:

98%

Form:

liquid

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Properties

assay

98%

form

liquid

optical activity

[α]23/D −17°, neat

optical purity

ee: ≥99% (GLC)

refractive index

n20/D 1.439 (lit.)

density

1.119 g/mL at 20 °C (lit.)

functional group

ester, hydroxyl

SMILES string

CC(C)OC(=O)[C@@H](O)[C@H](O)C(=O)OC(C)C

InChI

1S/C10H18O6/c1-5(2)15-9(13)7(11)8(12)10(14)16-6(3)4/h5-8,11-12H,1-4H3/t7-,8-/m0/s1

InChI key

XEBCWEDRGPSHQH-YUMQZZPRSA-N

Description

Application

Both D- and L-forms are reagents for kinetic resolution of racemic allylic alcohols and α-furfuryl amides by enantioselective epoxidation.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Regulatory Information

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Tetrahedron, 49, 2641-2641 (1993)

Aldrichimica Acta, 18, 53-53 (1985)

The Journal of Organic Chemistry, 59, 1444-1444 (1994)

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Global Trade Item Number

SKU	GTIN
227803-50G	04061837639227
227803-10G	04061838780942