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Merck
CN

227951

Chloro(1,5-cyclooctadiene)rhodium(I) dimer

98%, solid

Sustainability features

Synonym(s):

1,5-Cyclooctadienerhodium(I) chloride dimer, Bis(1,5-cyclooctadiene)dirhodium(I) dichloride, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer, [Rh(COD)Cl]2

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About This Item

Empirical Formula (Hill Notation):
C16H24Cl2Rh2
CAS Number:
Molecular Weight:
493.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
235-157-6
MDL number:
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Product Name

Chloro(1,5-cyclooctadiene)rhodium(I) dimer, 98%

Quality Segment

assay

98%

form

solid

reaction suitability

core: rhodium, reagent type: catalyst

sustainability

Sustainability features

mp

243 °C (dec.) (lit.)

greener alternative category

SMILES string

Cl[Rh].Cl[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;

InChI key

QSUDXYGZLAJAQU-MIXQCLKLSA-L

General description

This product aligns with one or more of the 12 Principles of Green Chemistry Find details here.

Application

Catalyst for coupling 1,3-dienes with activated hydrocarbons and for preparing chiral complexes.
Catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids


Pictograms

Exclamation mark

Signal Word

Warning

Hazard Codes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

WGK

WGK 3

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves



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