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227951

Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Brand: ALDRICH

98%, solid

Synonym(s):

1,5-Cyclooctadienerhodium(I) chloride dimer, Bis(1,5-cyclooctadiene)dirhodium(I) dichloride, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer, [Rh(COD)Cl]₂

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About This Item

Empirical Formula (Hill Notation):

C₁₆H₂₄Cl₂Rh₂

CAS Number:

12092-47-6

Molecular Weight:

493.08

NACRES:

NA.22

PubChem Substance ID:

24853665

UNSPSC Code:

12161600

EC Number:

235-157-6

MDL number:

MFCD00012415

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Properties

Product Name

Chloro(1,5-cyclooctadiene)rhodium(I) dimer, 98%

Quality Level

100

assay

98%

form

solid

reaction suitability

core: rhodium, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

243 °C (dec.) (lit.)

greener alternative category

Aligned,

SMILES string

Cl[Rh].Cl[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;

InChI key

QSUDXYGZLAJAQU-MIXQCLKLSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Catalyst for coupling 1,3-dienes with activated hydrocarbons and for preparing chiral complexes.

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Efficient and Selective Catalysts for Asymmetric Synthesis

Catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

pictograms

GHS07

signalword

Warning

hcodes

H319

pcodes

P264 - P280 - P305 + P351 + P338 - P337 + P313

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Tetrahedron Asymmetry, 4, 2279-2279 (1993)

The use of a [4 + 2] cycloaddition reaction for the preparation of a series of 'tethered' Ru(II)-diamine and aminoalcohol complexes.

Fung Kei Cheung et al.

Organic & biomolecular chemistry, 5(7), 1093-1103 (2007-03-23)

A series of catalysts have been prepared for use in the asymmetric transfer hydrogenation of ketones. The complexes were prepared using a [4 + 2] cycloaddition reaction at a key step in the reaction sequence. This provides a means for

Pure and Applied Chemistry. Chimie Pure Et Appliquee, 66, 1509-1509 (1994)

Global Trade Item Number

SKU	GTIN
227951-500MG	04061838781048
227951-50G	04061833410363
227951-5G	04061838781055