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229180

(+)-Diisopropyl L-tartrate

Name: (+)-Diisopropyl <SC>L</SC>-tartrate
Brand: ALDRICH

98%, optical purity ee: 99% (GLC)

Synonym(s):

L-(+)-Tartaric acid diisopropyl ester

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About This Item

Linear Formula:

[-CH(OH)CO₂CH(CH₃)₂]₂

CAS Number:

2217-15-4

Molecular Weight:

234.25

NACRES:

NA.22

PubChem Substance ID:

24853734

eCl@ss:

39021705

UNSPSC Code:

12352108

EC Number:

218-709-0

MDL number:

MFCD00064450

Beilstein/REAXYS Number:

1727863

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Properties

assay

98%

form

liquid

optical activity

[α]24/D +17°, neat

optical purity

ee: 99% (GLC)

refractive index

n20/D 1.439 (lit.)

bp

152 °C/12 mmHg (lit.)

density

1.114 g/mL at 25 °C (lit.)

SMILES string

CC(C)OC(=O)[C@H](O)[C@@H](O)C(=O)OC(C)C

InChI

1S/C10H18O6/c1-5(2)15-9(13)7(11)8(12)10(14)16-6(3)4/h5-8,11-12H,1-4H3/t7-,8-/m1/s1

InChI key

XEBCWEDRGPSHQH-HTQZYQBOSA-N

Description

Application

Both D- and L-forms are reagents for kinetic resolution of racemic allylic alcohols and α-furfuryl amides by enantioselective epoxidation.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

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Tetrahedron, 49, 2641-2641 (1993)

Aldrichimica Acta, 18, 53-53 (1985)

The Journal of Organic Chemistry, 59, 1444-1444 (1994)

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