229180
(+)-Diisopropyl L-tartrate
98%, optical purity ee: 99% (GLC)
Synonym(s):
L-(+)-Tartaric acid diisopropyl ester
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About This Item
Linear Formula:
[-CH(OH)CO2CH(CH3)2]2
CAS Number:
Molecular Weight:
234.25
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39021705
UNSPSC Code:
12352108
EC Number:
218-709-0
MDL number:
Beilstein/REAXYS Number:
1727863
InChI key
XEBCWEDRGPSHQH-HTQZYQBOSA-N
InChI
1S/C10H18O6/c1-5(2)15-9(13)7(11)8(12)10(14)16-6(3)4/h5-8,11-12H,1-4H3/t7-,8-/m1/s1
SMILES string
CC(C)OC(=O)[C@H](O)[C@@H](O)C(=O)OC(C)C
assay
98%
form
liquid
optical activity
[α]24/D +17°, neat
optical purity
ee: 99% (GLC)
bp
152 °C/12 mmHg (lit.)
density
1.114 g/mL at 25 °C (lit.)
Application
Both D- and L-forms are reagents for kinetic resolution of racemic allylic alcohols and α-furfuryl amides by enantioselective epoxidation.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
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Find documentation for the products that you have recently purchased in the Document Library.
The Journal of Organic Chemistry, 59, 1444-1444 (1994)
Aldrichimica Acta, 18, 53-53 (1985)
Tetrahedron, 49, 2641-2641 (1993)
Journal of the American Chemical Society, 115, 12208-12208 (1993)
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